Aluminate(1-), dihydrobis(2-(methoxy-kappaO)ethanolato-kappaO)-, sodium (1:1)

Base Information

• Chemical Name: Aluminate(1-), dihydrobis(2-(methoxy-kappaO)ethanolato-kappaO)-, sodium (1:1)
• CAS No.: 22722-98-1
• Deprecated CAS: 105644-84-6,123051-24-1,129270-49-1,144168-86-5,21595-42-6,21608-56-0,34542-18-2,60084-96-0,75339-25-2,2415256-35-6
• Molecular Formula: C6H16AlNaO4
• Molecular Weight: 202.162
• Hs Code.: 29319090
• European Community (EC) Number: 245-178-2
• Mol file: 22722-98-1.mol

Synonyms:dihydrobis(2-methoxyethoxy)aluminate;Red-Al;Vitride

Chemical Property of Aluminate(1-), dihydrobis(2-(methoxy-kappaO)ethanolato-kappaO)-, sodium (1:1)

Chemical Property:

• Appearance/Colour: clear to slightly hazy, colorless to light amber
• Vapor Pressure: 21 mm Hg ( 20 °C)
• Melting Point: 112oC
• Boiling Point: 396-402°C
• Flash Point: 40 °F
• PSA: 36.92000
• Density: 1.036 g/mL at 25 °C
• LogP: 0.45240
• Storage Temp.: Flammables area
• Sensitive.: Air & Moisture Sensitive
• Solubility.: Miscible with aromatic hydrocarbons, ether, tetrahydrofuran, dim
• Water Solubility.: reacts
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 4
• Exact Mass: 202.0761667
• Heavy Atom Count: 12
• Complexity: 14.4

Purity/Quality:

70%, ^*data from raw suppliers

SodiumBis(2-methoxyethoxy)aluminiumhydride(60%intoluene) ^*data from reagent suppliers

Safty Information:

• Pictogram(s): F, C
• Hazard Codes: F,C
• Statements: 11-14/15-34-48/20-63-65-67
• Safety Statements: 26-36/37/39-43-45-62-46-16-9

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: COCC[O-].COCC[O-].[Na+].[AlH2+]
• Uses: Reducing agent. Sodium bis(2-methoxyethoxy)aluminum hydride acts as a reducing agent in organic synthesis. It is used to prepare azoxyarenes, azoarenes and hydroazoarenes from nitroarenes. It plays an important role for the conversion of aldehydes, ketones, carboxylic acids, esters, acyl halides and anhydrides to primary alcohols. It is also employed in hydroaluminate alkenes and alkynes. It is utilized in the reduction of lactones and epoxides into diols. Further, it serves as a methylation reagent for aryl-activated compounds. In addition to this, it is involved in the reduction of amides, nitriles and amines to the corresponding amines. Red-Al? sodium bis(2-methoxyethoxy)aluminum hydride can be used as: ?????? A tosyl deprotecting agent.??????? A catalyst for crosslinking of polyvinylsilanes (PVS) by Si-Si dehydrocoupling reaction in the presence of group 4 metallocene complexes.??????? A reducing reagent for the synthesis of optically active N-protected amino alcohols and peptide alcohols.