n-(4-Bromophenyl)-n-nitrosoacetamide

Base Information

• Chemical Name: n-(4-Bromophenyl)-n-nitrosoacetamide
• CAS No.: 35920-23-1
• Molecular Formula: C8H7BrN2O2
• Molecular Weight: 243.06
• NSC Number: 105478
• DSSTox Substance ID: DTXSID80295775
• Wikidata: Q82035924
• Mol file: 35920-23-1.mol

Synonyms:35920-23-1;n-(4-bromophenyl)-n-nitrosoacetamide;NSC105478;SCHEMBL11349816;DTXSID80295775;NSC-105478

Chemical Property of n-(4-Bromophenyl)-n-nitrosoacetamide

Chemical Property:

• Vapor Pressure: 0.000583mmHg at 25°C
• Boiling Point: 310.9°Cat760mmHg
• Flash Point: 141.8°C
• Density: 1.57g/cm³
• XLogP3: 1.7
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 1
• Exact Mass: 241.96909
• Heavy Atom Count: 13
• Complexity: 202

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC(=O)N(C1=CC=C(C=C1)Br)N=O

Technology Process of n-(4-Bromophenyl)-n-nitrosoacetamide

There total 3 articles about n-(4-Bromophenyl)-n-nitrosoacetamide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

4-bromoacetanilide (103-88-8) → acetic acid-(4-bromo-N-nitroso-anilide) (35920-23-1)

Guidance literature:

With potassium acetate; phosphorus pentoxide; acetic acid; nitrosylchloride; Reagens 4: Acetanhydrid;

DOI:10.1039/df9470200279

Reference yield:

N-nitrosoacetanilide (938-81-8) + ethenyltrimethylsilane (754-05-2) → acetic acid-(4-bromo-N-nitroso-anilide) (35920-23-1) + 1-(trimethylsilyl)-2-phenylethene (19372-00-0) + trimethyl(1-phenylvinyl)silane (1923-01-9)

Guidance literature:

With bis(dibenzylideneacetone)-palladium⁽⁰⁾; In acetonitrile; at 40 ℃; for 2h; Product distribution; var. times and reagents, other alkenyl silanes;

DOI:10.1021/jo00383a019

Reference yield:

→ acetic acid-(4-bromo-N-nitroso-anilide) (35920-23-1)

Guidance literature:

p-Bromacetanilid, NOCl;

upstream raw materials:

4-bromoacetanilide

N-nitrosoacetanilide

ethenyltrimethylsilane

Downstream raw materials:

2-(4-bromophenyl]pyridine

4-(4-bromophenyl)pyridine

4-bromo-benzene-standarddiazohydroxide-⁽¹⁾

N-(4-bromo-phenyl)-N-nitroso-hydroxylamine