4,N,N',N''-Tetramethyl-2,6,7-triaza-1-phosphabicyclo(2.2.2)octane

Base Information

• Chemical Name: 4,N,N',N''-Tetramethyl-2,6,7-triaza-1-phosphabicyclo(2.2.2)octane
• CAS No.: 14418-26-9
• Molecular Formula: C8H18 N3 P
• Molecular Weight: 187.225
• DSSTox Substance ID: DTXSID60162638
• Nikkaji Number: J770.619G
• Wikidata: Q83031357
• Mol file: 14418-26-9.mol

Synonyms:14418-26-9;4,N,N',N''-Tetramethyl-2,6,7-triaza-1-phosphabicyclo(2.2.2)octane;4,N,N',N''-Tetramethyl-2,6,7-triaza-1-phosphabicyclo[2.2.2]octane;2,4,6,7-Tetramethyl-2,6,7-triaza-1-phosphabicyclo[2.2.2]octane;DTXSID60162638;4,N,N',N"-Tetramethyl-2,6,7-triaza-1-phosphabicyclo[2.2.2]octane

Chemical Property of 4,N,N',N''-Tetramethyl-2,6,7-triaza-1-phosphabicyclo(2.2.2)octane

Chemical Property:

• Vapor Pressure: 0.256mmHg at 25°C
• Boiling Point: 205°Cat760mmHg
• Flash Point: 77.8°C
• Density: g/cm³
• XLogP3: 0.8
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 0
• Exact Mass: 187.12383458
• Heavy Atom Count: 12
• Complexity: 166

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC12CN(P(N(C1)C)N(C2)C)C

Technology Process of 4,N,N',N''-Tetramethyl-2,6,7-triaza-1-phosphabicyclo(2.2.2)octane

There total 1 articles about 4,N,N',N''-Tetramethyl-2,6,7-triaza-1-phosphabicyclo(2.2.2)octane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

N,N'-Bis-(5,5-dimethyl-[1,3,2]dioxaphosphinan-2-yl)-2-{[(5,5-dimethyl-[1,3,2]dioxaphosphinan-2-yl)-methyl-amino]-methyl}-2,N,N'-trimethyl-propane-1,3-diamine → 2,2'-(2,2-dimethyl-1,3-propanedioxy)-5,5-dimethyl-1,3,2-dioxaphosphorinane-5',5'-dimethyl-1',3',2'-dioxaphosphorinane (59609-05-1) + 2,6,7-trimethyl-4-methyl-2,6,7-triaza-1-phosphaicyclo<2.2.2>octane (14418-26-9)

Guidance literature:

at 110 ℃; for 1h; under 25 Torr;

Reference yield: 72.0%

silver tetrafluoroborate (14104-20-2) + sodium tetraphenyl borate (143-66-8) + 2,6,7-trimethyl-4-methyl-2,6,7-triaza-1-phosphaicyclo<2.2.2>octane (14418-26-9) → Ag(P(N(CH3)CH2)3CCH3)3(1+)*B(C6H5)4(1-)=Ag(P(N(CH3)CH2)3CCH3)3B(C6H5)4 (87884-07-9)

Guidance literature:

In ethanol; ppt. washed with ethanol, recrystn. with difficulty from acetone/ethanol;

Downstream raw materials:

Ag(P(N(CH₃)CH₂)3CCH₃)3⁽¹⁺⁾*B(C₆H₅)4^(1-)=Ag(P(N(CH₃)CH₂)3CCH₃)3B(C₆H₅)4