Nitrosyl bromide

Base Information

• Chemical Name: Nitrosyl bromide
• CAS No.: 13444-87-6
• Molecular Formula: BrNO
• Molecular Weight: 109.91
• DSSTox Substance ID: DTXSID90158701
• Nikkaji Number: J96.079I
• Wikipedia: Nitrosyl bromide,Nitrosyl_bromide
• Wikidata: Q1278807
• Mol file: 13444-87-6.mol

Synonyms:Nitrosyl bromide;Nitrosyl bromide ((NO)Br);13444-87-6;Nitrosylbromid;BrNO;NOBr;Br-N-O;DTXSID90158701;Q1278807

Chemical Property of Nitrosyl bromide

Chemical Property:

• Vapor Pressure: 1940mmHg at 25°C
• Boiling Point: °Cat760mmHg
• Flash Point: °C
• Density: 2.4g/cm³
• XLogP3: 0.8
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 0
• Exact Mass: 108.91633
• Heavy Atom Count: 3
• Complexity: 12.3

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: N(=O)Br

Technology Process of Nitrosyl bromide

There total 13 articles about Nitrosyl bromide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

bromopicrin (464-10-8) → carbonyl dibromide (593-95-3) + nitrosyl bromide (13444-87-6)

Guidance literature:

With sulfuric acid; 130-135°C with concd. H2SO4;

Reference yield:

bromine nitrate (40423-14-1) + oxygen → bromine dioxide (21255-83-4,1210275-22-1) + Nitrogen dioxide (10102-44-0) + nitrosyl bromide (13444-87-6)

Guidance literature:

In gas; Irradiation (UV/VIS); flash photolysis at 248-, 355 nm, large excess of BrONO2 over O, 227- 339 K, 16-157 Torr; Kinetics;

DOI:10.1021/jp001947q

Reference yield:

hydrogen bromide (10035-10-6,12258-64-9) + nitrosylchloride (2696-92-6) → hydrogenchloride (7647-01-0,15364-23-5) + nitrosyl bromide (13444-87-6)

Guidance literature:

In neat (no solvent); at temp. of liquid air;;

upstream raw materials:

propyl bromide

isopropyl bromide

hydrogen bromide

nitrosylchloride

Downstream raw materials:

bromine

nitrogen(II) oxide

potassium nitrite

potassium bromide

Refernces

• 1、 Bro?ske,Zabel. "Kinetics of the gas-phase reaction of BrNO2 with NO". . p. 8626 - 8631. Retrieved 2007/10/03.
• 2、 Wyttenbach, Thomas,Bowers, Michael T.. "Ion-Molecule Reactions of Vibrationally State-Selected NO+ with Small Alkyl Halides". . p. 8920 - 8929. Retrieved 2007/10/02.