copper(2+) 2-carboxypiperidin-1-ide 6-carboxy-2H-pyridin-1-ide (1:1:1)

Base Information

• Chemical Name: copper(2+) 2-carboxypiperidin-1-ide 6-carboxy-2H-pyridin-1-ide (1:1:1)
• CAS No.: 14050-01-2
• Molecular Formula: C₁₂H₈CuN₂O₄
• Molecular Weight: 307.753
• Mol file: 14050-01-2.mol

Synonyms:Copper,bis(2-pyridinecarboxylato-N1,O2)-; Copper, bis(picolinato)- (7CI,8CI);Picolinic acid, copper complex (6CI); 2-Pyridinecarboxylic acid, coppercomplex; Copper(II) picolinate; NSC 21209

Chemical Property of copper(2+) 2-carboxypiperidin-1-ide 6-carboxy-2H-pyridin-1-ide (1:1:1)

Chemical Property:

• Vapor Pressure: 0.0026mmHg at 25°C
• Boiling Point: 265.8°C at 760 mmHg
• Flash Point: 114.5°C

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of copper(2+) 2-carboxypiperidin-1-ide 6-carboxy-2H-pyridin-1-ide (1:1:1)

There total 17 articles about copper(2+) 2-carboxypiperidin-1-ide 6-carboxy-2H-pyridin-1-ide (1:1:1) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

2,2'-Pyridil (492-73-9) + copper (12775-96-1,15158-11-9,15721-63-8,16941-75-6,17493-86-6,19498-52-3,20499-83-6,20499-84-7,20499-85-8,20499-86-9,20573-10-8,20573-11-9,21595-51-7,21595-52-8,22206-52-6,26445-28-3,28959-95-7,37362-93-9,39417-05-5,54603-16-6,54603-23-5,54603-32-6,54603-40-6,54603-48-4,54603-81-5,54603-89-3,56316-56-4,95985-91-4,122297-32-9,7440-50-8) → copper(II) pyridine-2-carboxylate (14050-01-2,21882-07-5)

Guidance literature:

With dioxygen; In pyridine; stirred at room temp. under an atmosphere of oxygen for 3.5 h; evapn. of pyridine under reduced pressure, triturated with diethyl ether, filtered off, washed with diethyl ether, dried in vac.; elem. anal.;

Reference yield: 95.0%

2-Cyanopyridine (100-70-9,1232006-36-8) + copper(II) choride dihydrate + water (7732-18-5) → copper(II) pyridine-2-carboxylate (14050-01-2,21882-07-5)

Guidance literature:

In water; refluxing (20 h); filtering, washing (EtOH), drying (vac.);

DOI:10.1016/S0277-5387(98)00259-9

Reference yield: 78.0%

2-Picolinic acid (98-98-6) + copper (12775-96-1,15158-11-9,15721-63-8,16941-75-6,17493-86-6,19498-52-3,20499-83-6,20499-84-7,20499-85-8,20499-86-9,20573-10-8,20573-11-9,21595-51-7,21595-52-8,22206-52-6,26445-28-3,28959-95-7,37362-93-9,39417-05-5,54603-16-6,54603-23-5,54603-32-6,54603-40-6,54603-48-4,54603-81-5,54603-89-3,56316-56-4,95985-91-4,122297-32-9,7440-50-8) → bis(2-pyridinecarboxylato)copper(II)complex (14050-01-2,21882-07-5)

Guidance literature:

With potassium chloride; In water; N,N-dimethyl-formamide; for 1.5h; Electrolysis;

DOI:10.1134/S1070363221090139

upstream raw materials:

2-Picolinic acid

copper diacetate

sodium dicyanamide

3,4-bis(2-pyridylmethylthio)-5-methyltoluene

Downstream raw materials:

copper(II) pyridine-2-carboxylate

Refernces

• 1、 Papaefstathiou, Giannis S.,Raptopoulou, Catherine P.,Tsohos, Alexandros,Terzis, Aris,Bakalbassis, Evangelos G.,Perlepes, Spyros P.. "Alcoholysis of 2,2'-pyridil, (2-C5H4N)C(O)C(O)(2-C5H4N), iin the presence of copper(II): A family of planar pentanuclear copper(II) complexes stabilized by [(2-C5H4N)C(O)(OR)C(O)(OR)(2-C5H4N)]2- and carboxylate ligands". . p. 4658 - 4662. Retrieved 2000.
• 2、 Zurowska, Bogumi?a,Ochocki, Justyn,Mroziński, Jerzy,Ciunik, Zbigniew,Reedijk, Jan. "Synthesis, spectroscopic and magnetostructural evidence for the formation of Cu(II) complexes of pyridyl-2-carboxylate (2-pca) and quinolyl-2-carboxylate (2-qca) as a result of a novel oxidative P-dealkylation reaction of diethyl 2-pyridylmethylphosphonate (2-pmpe) and diethyl 2-quinolylmethylphosphonate (2-qmpe) ligands". . p. 755 - 763. Retrieved 2004.
• 3、 Andriychenko, E. O.,Bespalov, A. V.,Bovyka, V. E.,Bukov, N. N.,Zelenov, V. I.. "Electrochemical Synthesis and Characterization of Copper(II) and Zinc(II) Coordination Compounds with Nicotinic and Picolinic Acids". . p. 1697 - 1705. Retrieved 2021/11/01.
• 4、 Sarkar, Sandipan,Sen, Supriti,Dey, Sourav,Zangrando, Ennio,Chattopadhyay, Pabitra. "Coordination behavior of 3,4-bis(2-pyridylmethylthio)toluene with copper(II) ions: Synthesis, structural characterization and reactivity, and DNA binding study of the dinuclear copper(II) complex". . p. 3157 - 3163. Retrieved 2011/02/18.