2-Allyloxy-m-anisic acid

Base Information

• Chemical Name: 2-Allyloxy-m-anisic acid
• CAS No.: 96619-88-4
• Molecular Formula: C11H12 O4
• Molecular Weight: 208.214
• European Community (EC) Number: 306-200-7
• DSSTox Substance ID: DTXSID10242373
• Nikkaji Number: J382.898K
• Wikidata: Q83126047
• Mol file: 96619-88-4.mol

Synonyms:2-Allyloxy-m-anisic acid;96619-88-4;EINECS 306-200-7;2-Allyloxy-3-methoxy-benzoic acid;SCHEMBL668774;DTXSID10242373;YOAIHTMTCQXBPI-UHFFFAOYSA-N;AKOS000282497;3-Methoxy-2-(2-propenyloxy)benzoic acid

Chemical Property of 2-Allyloxy-m-anisic acid

Chemical Property:

• Vapor Pressure: 3.29E-05mmHg at 25°C
• Boiling Point: 340.6°Cat760mmHg
• Flash Point: 131.6°C
• PSA: 55.76000
• Density: 1.169g/cm³
• LogP: 1.95820
• XLogP3: 2.4
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 5
• Exact Mass: 208.07355886
• Heavy Atom Count: 15
• Complexity: 227

Purity/Quality:

98%Min ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: COC1=CC=CC(=C1OCC=C)C(=O)O

Technology Process of 2-Allyloxy-m-anisic acid

There total 8 articles about 2-Allyloxy-m-anisic acid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

C14H16O4 → 2-(allyloxy)-3-methoxybenzoic acid (96619-88-4)

Guidance literature:

With sodium hydroxide; In ethanol; water; at 80 ℃; for 1h;

DOI:10.1039/c9ob00637k

Reference yield:

3-methoxysalicylic acid (877-22-5) → 2-(allyloxy)-3-methoxybenzoic acid (96619-88-4)

Guidance literature:

Multi-step reaction with 3 steps

1: sulfuric acid

2: potassium carbonate; potassium iodide; methylethyl ketone

3: methanolic KOH-solution

With potassium hydroxide; sulfuric acid; potassium carbonate; 2,4-dimethylpentan-3-one; potassium iodide;

Reference yield:

2-allyloxy-3-methoxy-benzaldehyde (23343-06-8) → 2-(allyloxy)-3-methoxybenzoic acid (96619-88-4)

Guidance literature:

With Jones reagent; In acetone; at 0 - 25 ℃; for 24h;

DOI:10.1039/c5cc10245f

upstream raw materials:

3-methoxy-2-(2-propenyloxy)benzoic acid, methyl ester

3-methoxysalicylic acid

3-methoxymethylsalicylate

allyl bromide

Downstream raw materials:

6-allylguaicol

5-allyl-2-hydroxy-3-methoxybenzoic acid