Methyl 4'-bromo[1,1'-biphenyl]-4-carboxylate

Base Information

Chemical Name:Methyl 4'-bromo[1,1'-biphenyl]-4-carboxylate
CAS No.:89901-03-1
Molecular Formula:C14H11BrO2
Molecular Weight:291.144
Hs Code.:2916399090
European Community (EC) Number:687-289-2
DSSTox Substance ID:DTXSID30353273
Nikkaji Number:J2.234.810H
Wikidata:Q72488415
Mol file:89901-03-1.mol

Synonyms:89901-03-1;methyl 4'-bromo[1,1'-biphenyl]-4-carboxylate;methyl 4-(4-bromophenyl)benzoate;Methyl 4'-bromo-[1,1'-biphenyl]-4-carboxylate;methyl 4'-bromobiphenyl-4-carboxylate;[1,1'-Biphenyl]-4-carboxylic acid, 4'-bromo-, methyl ester;[1,1'-Biphenyl]-4-carboxylicacid, 4'-bromo-, methyl ester;Methyl4'-bromo-[1,1'-biphenyl]-4-carboxylate;4'-Bromo-biphenyl-4-carboxylic acid methyl ester;YSZC804;SCHEMBL2386975;DTXSID30353273;AMY33202;MFCD00496638;AKOS002679587;methyl 4'-bromo-biphenyl-4-carboxylate;Methyl 4-(4-bromophenyl)benzoate, 95%;CS-0131255;FT-0680234;4'-Bromobiphenyl-4-carboxylic acid methyl ester;2W-0305;J-522311;METHYL 4-BROMO[1,1-BIPHENYL]-4-CARBOXYLATE

Suppliers and Price of Methyl 4'-bromo[1,1'-biphenyl]-4-carboxylate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

TRC
Methyl4''-Bromo-[1,1''-biphenyl]-4-carboxylate
1g
$ 180.00

SynQuest Laboratories
Methyl 4'-bromo-[1,1'-biphenyl]-4-carboxylate
10 g
$ 856.00

SynQuest Laboratories
Methyl 4'-bromo-[1,1'-biphenyl]-4-carboxylate
5 g
$ 464.00

SynQuest Laboratories
Methyl 4'-bromo-[1,1'-biphenyl]-4-carboxylate
1 g
$ 200.00

Sigma-Aldrich
Methyl 4-(4-bromophenyl)benzoate 95%
1g
$ 134.00

Matrix Scientific
Methyl 4'-bromo[1,1'-biphenyl]-4-carboxylate >95%
5g
$ 665.00

Matrix Scientific
Methyl 4'-bromo[1,1'-biphenyl]-4-carboxylate >95%
1g
$ 280.00

Crysdot
Methyl4'-bromo-[1,1'-biphenyl]-4-carboxylate 97%
1g
$ 53.00

Biosynth Carbosynth
4'-Bromo-biphenyl-4-carboxylic acid methyl ester
250 mg
$ 60.00

Biosynth Carbosynth
4'-Bromo-biphenyl-4-carboxylic acid methyl ester
500 mg
$ 95.00

Total 25 raw suppliers

Chemical Property of Methyl 4'-bromo[1,1'-biphenyl]-4-carboxylate

Chemical Property:

Melting Point:146-148 °C
Boiling Point:382.7 °C at 760 mmHg
Flash Point:185.3 °C
PSA：26.30000
Density:1.394 g/cm³
LogP:3.90270
Water Solubility.:Slightly soluble in water.
XLogP3:4.6
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:3
Exact Mass:289.99424
Heavy Atom Count:17
Complexity:251

Purity/Quality:

99%, ^*data from raw suppliers

Methyl4''-Bromo-[1,1''-biphenyl]-4-carboxylate ^*data from reagent suppliers

Safty Information:

Pictogram(s): Xi,N
Hazard Codes:Xi,N
Statements: 36/37/38-50/53-41
Safety Statements: 26-36/37/39-61-60-39

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:COC(=O)C1=CC=C(C=C1)C2=CC=C(C=C2)Br
Uses It is employed in the design, synthesis, and biological evaluation of novel nonsteroidal farnesoid x receptor (fxr) antagonists.

Technology Process of Methyl 4'-bromo[1,1'-biphenyl]-4-carboxylate

There total 13 articles about Methyl 4'-bromo[1,1'-biphenyl]-4-carboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

: 89901-03-1
methyl 4’-bromo-[1,1’-diphenyl]-4-carboxylate

Guidance literature:: With chloro[tris(para-trifluoromethylphenyl)phosphine]gold (I); In methanol; at 20 ℃; for 16h; Irradiation; Inert atmosphere;

Reference yield: 93.62%

: 619-44-3
methyl 4-iodobenzoate

: 5467-74-3
4-Bromophenylboronic acid

: 89901-03-1
methyl 4’-bromo-[1,1’-diphenyl]-4-carboxylate

Guidance literature:: With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; potassium carbonate; In toluene; at 90 ℃; for 12h; Inert atmosphere;

Reference yield: 90.0%

: 67-56-1
methanol

: 5731-11-3
4-(4-bromophenyl)benzoic acid

: 89901-03-1
methyl 4’-bromo-[1,1’-diphenyl]-4-carboxylate

Guidance literature:: With 4-methyl-morpholine; benzotriazol-1-ol; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride;
DOI:10.1021/ja9037609