Silane, trimethyl((4-(methylthio)phenyl)methyl)-

Base Information

• Chemical Name: Silane, trimethyl((4-(methylthio)phenyl)methyl)-
• CAS No.: 59163-55-2
• Molecular Formula: C11H18SSi
• Molecular Weight: 210.415
• DSSTox Substance ID: DTXSID30207888
• Wikidata: Q83081896
• Mol file: 59163-55-2.mol

Synonyms:Silane, trimethyl((4-(methylthio)phenyl)methyl)-;59163-55-2;Silane,trimethyl[[4-(methylthio)phenyl]methyl]-;DTXSID30207888

Chemical Property of Silane, trimethyl((4-(methylthio)phenyl)methyl)-

Chemical Property:

• Vapor Pressure: 0.0169mmHg at 25°C
• Boiling Point: 263.3°Cat760mmHg
• Flash Point: 113.1°C
• Density: 0.94g/cm³
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 3
• Exact Mass: 210.08984828
• Heavy Atom Count: 13
• Complexity: 143

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C[Si](C)(C)CC1=CC=C(C=C1)SC

Technology Process of Silane, trimethyl((4-(methylthio)phenyl)methyl)-

There total 1 articles about Silane, trimethyl((4-(methylthio)phenyl)methyl)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

Dimethyldisulphide (624-92-0) + p-<(trimethylsilyl)methyl>bromobenzene (17095-20-4) → 4-methylsulfidebenzyltrimethylsilane (59163-55-2)

Guidance literature:

Multistep reaction; (i) Mg, (ii) /BRN= 1730824/;

DOI:10.1039/P29760000306

Reference yield: 72.0%

N-phenyl-maleimide (941-69-5) + 4-methylsulfidebenzyltrimethylsilane (59163-55-2) → 3-(4-(methylthio)benzyl)-1-phenylpyrrolidine-2,5-dione

Guidance literature:

With 9-(2-mesityl)-10-methylacridinium perchlorate; In chloroform; at 20 ℃; for 18h; Irradiation; Sealed tube;

DOI:10.1039/c8cc10239b

Reference yield:

4-methylsulfidebenzyltrimethylsilane (59163-55-2) → 4-methylphenyl methylsulfide (623-13-2)

Guidance literature:

With potassium trimethylsilonate; In dimethyl sulfoxide; at 70 ℃; for 6h; Sealed tube; Schlenk technique;

DOI:10.1021/acs.joc.7b03139

upstream raw materials:

Dimethyldisulphide

p-<(trimethylsilyl)methyl>bromobenzene

Downstream raw materials:

(4-Methanesulfinyl-benzyl)-trimethyl-silane

4-methylphenyl methylsulfide