2-Methyl-4-(2,6,6-trimethyl-2-cyclohexenyl)-2-butenal

Base Information

Chemical Name:2-Methyl-4-(2,6,6-trimethyl-2-cyclohexenyl)-2-butenal
CAS No.:68555-62-4
Molecular Formula:C14H22O
Molecular Weight:206.328
Hs Code.:
European Community (EC) Number:271-439-5
Nikkaji Number:J76.406J
Mol file:68555-62-4.mol

Synonyms:SCHEMBL3503433;EINECS 271-439-5;2-Methyl-4-(2,6,6-trimethyl-2-cyclohexenyl)-2-butenal;2-Methyl-4-(2,6,6-trimethyl-2-cyclohexen-1-yl)-2-butenal

Suppliers and Price of 2-Methyl-4-(2,6,6-trimethyl-2-cyclohexenyl)-2-butenal

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

TRC
(E)-2-Methyl-4-(2,6,6-trimethylcyclohex-2-en-1-yl)but-3-enal
500mg
$ 75.00

American Custom Chemicals Corporation
VELTONAL 98.00%
1KG
$ 7580.27

Total 7 raw suppliers

Chemical Property of 2-Methyl-4-(2,6,6-trimethyl-2-cyclohexenyl)-2-butenal

Chemical Property:

Boiling Point:288.6°Cat760mmHg
Flash Point:121.1°C
PSA：17.07000
Density:0.881g/cm³
LogP:3.76010
XLogP3:3.4
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:3
Exact Mass:206.167065321
Heavy Atom Count:15
Complexity:295

Purity/Quality:

98%min ^*data from raw suppliers

(E)-2-Methyl-4-(2,6,6-trimethylcyclohex-2-en-1-yl)but-3-enal ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:CC1=CCCC(C1CC=C(C)C=O)(C)C
Isomeric SMILES:CC1=CCCC(C1C/C=C(\C)/C=O)(C)C

Technology Process of 2-Methyl-4-(2,6,6-trimethyl-2-cyclohexenyl)-2-butenal

There total 5 articles about 2-Methyl-4-(2,6,6-trimethyl-2-cyclohexenyl)-2-butenal which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 79-77-6,14901-07-6
(E)-β-ionone

: 105-39-5
chloroacetic acid ethyl ester

: 56013-05-9
(RS)-(E)-2-methyl-4-(2',6',6'-trimethyl-1'-cyclohexenyl)-3-butenal

: 68555-62-4
2-methyl-4-(2,6,6-trimethyl-cyclohex-2-enyl)-crotonaldehyde

Guidance literature:: With sodium methylate; benzene; at 0 ℃; Behandeln des nach dem Ansaeuern isolierten Ester-Gemisches mit KOH in Methanol oder Aethanol und Erhitzen des Reaktionsprodukts mit Pyridin unter vermindertem Druck auf 100-210grad;

Reference yield:

: 127-41-3,6901-97-9,14398-36-8,24190-29-2,30685-95-1,31798-12-6,52340-45-1,67529-94-6,67529-95-7
alpha-ionone

: 105-39-5
chloroacetic acid ethyl ester

: 68555-62-4
2-methyl-4-(2,6,6-trimethyl-cyclohex-2-enyl)-crotonaldehyde

Guidance literature:: With diethyl ether; sodium methylate; at -60 ℃; substance of bp _0.0001: 45 degree Celsius; Behandeln des nach dem Ansaeuern isolierten Ester-Gemisches mit aethanol. KOH und Erhitzen des Reaktionsprodukts mit Kupfer-Pulver unter 15 Torr auf 130grad;

Reference yield:

: 127-41-3,6901-97-9,14398-36-8,24190-29-2,30685-95-1,31798-12-6,52340-45-1,67529-94-6,67529-95-7
alpha-ionone

: 105-39-5
chloroacetic acid ethyl ester

: 68555-62-4
2-methyl-4-(2,6,6-trimethyl-cyclohex-2-enyl)-crotonaldehyde

Guidance literature:: With sodium ethanolate; at -5 - 0 ℃; (+-)-2-methyl-4-<2.2.6-trimethyl-cyclohexen-(5)-yl>-buten-(2)-al-(1); Erwaermen des Reaktionsprodukts mit 10prozentig. wss. Kalilauge auf 30-35grad und Erhitzen der nach dem Ansaeuern mit wss. H₂SO₄ erhaltenen Carbonsaeure unter 10 Torr auf Siedetemperatur;