4-[2,6,6-trimethyl-cyclohex-1-en-1-yl]-2-methyl-but-2-en-1-ol

Base Information

• Chemical Name: 4-[2,6,6-trimethyl-cyclohex-1-en-1-yl]-2-methyl-but-2-en-1-ol
• CAS No.: 14398-39-1
• Molecular Formula: C₁₄H₂₄O
• Molecular Weight: 208.344
• Mol file: 14398-39-1.mol

Synonyms:4-[2,6,6-trimethyl-cyclohex-1-en-1-yl]-2-methyl-but-2-en-1-ol

Chemical Property of 4-[2,6,6-trimethyl-cyclohex-1-en-1-yl]-2-methyl-but-2-en-1-ol

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of 4-[2,6,6-trimethyl-cyclohex-1-en-1-yl]-2-methyl-but-2-en-1-ol

There total 2 articles about 4-[2,6,6-trimethyl-cyclohex-1-en-1-yl]-2-methyl-but-2-en-1-ol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

(E)-2-methyl-4-(2,6,6-trimethyl-1-cyclohexenyl)-2-butenal (14398-40-4) → 4-[2,6,6-trimethyl-cyclohex-1-en-1-yl]-2-methyl-but-2-en-1-ol (14398-39-1)

Guidance literature:

With hydrogen; potassium isopropoxide; [Ru(Cl)2(ethP₂(NH)2)]; In isopropyl alcohol; at 60 ℃; for 24h; under 33752.7 Torr;

DOI:10.1002/chem.200304884

Reference yield:

2-methyl-4-(2,6,6-trimethyl-cyclohex-2-enyl)-crotonaldehyde (68555-62-4) → 4-[2,6,6-trimethyl-cyclohex-1-en-1-yl]-2-methyl-but-2-en-1-ol (14398-39-1)

Guidance literature:

With lithium aluminium tetrahydride; diethyl ether; at 0 ℃;

Reference yield:

carbon tetrabromide (558-13-4) + 4-[2,6,6-trimethyl-cyclohex-1-en-1-yl]-2-methyl-but-2-en-1-ol (14398-39-1) → (2E)-1-bromo-2-methyl-4-(2,6,6-trimethyl-1-cyclohexen-1-yl)-2-butene

Guidance literature:

With triphenylphosphine; In dichloromethane;

upstream raw materials:

2-methyl-4-(2,6,6-trimethyl-cyclohex-2-enyl)-crotonaldehyde

(E)-2-methyl-4-(2,6,6-trimethyl-1-cyclohexenyl)-2-butenal