Methanol-d4

Base Information

• Chemical Name: Methanol-d4
• CAS No.: 811-98-3
• Molecular Formula: CD4O
• Molecular Weight: 36.0104
• Hs Code.: 28459000
• European Community (EC) Number: 212-378-6
• DSSTox Substance ID: DTXSID801010038
• Nikkaji Number: J193.190C
• Wikipedia: Deuterated_methanol
• Wikidata: Q1100804
• Mol file: 811-98-3.mol

Synonyms:Methanol-d4;811-98-3;Tetradeuteromethanol;Methan-d3-ol-d;Perdeuteromethanol;Methyl Alcohol-d4;(2H4)Methanol;trideuterio(deuteriooxy)methane;Methyl-d3 alcohol d;CD3OD;Methanol D4;EINECS 212-378-6;methyl-d3 alcohol-d;MFCD00044637;Methanol-d4, 99.8 atom % D;Methanol-d4, >=99.8 atom % D;Deuterated methanol;Methanol-d4, "100%", 99.96 atom % D;Methyl-d3 alcohol-d, cont. 0.03 v/v% TMS;Methanol-d4, >=99.8 atom % D, contains 0.03 % (v/v) TMS;Methyl Alcohol D4;((2)H4)methanol;CD4O;METHANOL (D4);Methyl-12C,d3 alcohol-d;Methanol-D4 >99.5%;trideuterio deuteriooxy methane;Methanol-d4, 99 atom % D;((2)H3)methan((2)H)ol;C-D4-O;CHEBI:156265;DTXSID801010038;MFCD08460912;AKOS015917660;CS-T-57790;M1869;M1888;Methanol D4 >99.8%(+0.03% TMS);Methanol-D4 >99.5% (+ 0.03%TMS);Methanol-d4, >=99.8 atom % D, anhydrous;Methanol-d4, anhydrous, >=99.8 atom % D;Q1100804;Methanol-12C,d4, 99.95 atom % 12C, 99.8 atom % D;Methanol-d4, >=99.8 atom % D, contains 0.1 % (v/v) TMS;Methanol-d4, >=99.8 atom % D, contains 1 % (v/v) TMS;Methanol-d4, 99.8 atom % D, contains 0.03 % (v/v) TMS;Methanol-d4, reagent grade, >=99 atom % D, >=99% (CP);Methanol-d4, "100%", >=99.96 atom % D, >=99% (CP);Methanol-d4, >=99.8 atom % D, contains 0.05 % (v/v) TMS;Methanol-d4, "100%", >=99.96 atom % D, contains 0.03 % (v/v) TMS

Chemical Property of Methanol-d4

Chemical Property:

• Appearance/Colour: colourless liquid
• Vapor Pressure: 265mmHg at 25°C
• Melting Point: -99 °C
• Refractive Index: n20/D 1.326(lit.)
• Boiling Point: 48.1 °C at 760 mmHg
• Flash Point: 11.1 °C
• PSA: 20.23000
• Density: 0.847 g/cm³
• LogP: -0.39150
• Storage Temp.: Flammables area
• Water Solubility.: Miscible with water, ethanol, ether, acetone and chloroform.
• XLogP3: -0.5
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 0
• Exact Mass: 36.051321731
• Heavy Atom Count: 2
• Complexity: 2

Purity/Quality:

99% ^*data from raw suppliers

Methanol-D4 >99.5% (+ 0.03%TMS) ^*data from reagent suppliers

Safty Information:

• Pictogram(s): F,T
• Hazard Codes: F,T
• Statements: 11-23/24/25-39/23/24/25
• Safety Statements: 7-16-36/37-45

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: CO
• Isomeric SMILES: [2H]C([2H])([2H])O[2H]
• Uses: Methanol-d4 may be used as a solvent to analyze the rate of exchange of methoxyl group in camphor and norcamphor dimethyl ketals.

Technology Process of Methanol-d4

There total 29 articles about Methanol-d4 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

N-(dimethylphosphoryl)ethyleneimine (469-47-6) → 1-deuteroaziridine (5381-40-8) + d(4)-methanol (811-98-3) + sodium dimethyl phosphate (32586-82-6)

Guidance literature:

With deuteriated sodium hydroxide; In water-d2; at 31 ℃; Product distribution; Rate constant; dependence of relative reactivity of the P-O and P-N bond on OD^(1-) concentration;

Reference yield:

carbon dioxide (124-38-9,18923-20-1) → methane (558-20-3) + d(4)-methanol (811-98-3) + carbon monoxide (201230-82-2)

Guidance literature:

With deuterium; at 170 ℃; under 750.075 Torr; Reagent/catalyst; Catalytic behavior;

DOI:10.1021/jacs.9b10873

Reference yield:

1,3-dimethyl-1-triazene (3585-32-8,115246-94-1,115246-96-3,467426-36-4) → <2H1>methan<2H>ol (53952-42-4) + deuteromethanol (1455-13-6) + d(4)-methanol (811-98-3) + CD2HOD (53952-43-5) + methylamine (74-89-5)

Guidance literature:

With phosphate buffer; In water; at 25 ℃; Rate constant; Product distribution; Mechanism; further buffer, different pH; solvent isotope effects were measured;

DOI:10.1021/ja00273a029

upstream raw materials:

1,1,1-trideuteromethanol

Trideutero-methylbromid

diazomethane

N-(dimethylphosphoryl)ethyleneimine

Downstream raw materials:

1,1,1-trideuteromethanol

1-ethenyl-4-methylbenzene

3-methylstyrene

1-methyl-2-vinyl-benzene

Refernces

Rotational Isomerism in Fluorene Derivatives. XVI. Conformational Equilibria of 9-Substituted 9-(2'-Bromomethylphenyl)fluorene Derivatives

10.1246/bcsj.62.2093

The research focused on the rotational isomerism in fluorene derivatives, specifically examining the conformational equilibria of 9-substituted 9-(2-bromomethylphenyl)fluorene derivatives. The purpose of the study was to understand the conformational equilibria (ap-sp) of these compounds based on the kinetic data for internal rotation obtained through HNMR spectroscopy. The researchers synthesized eight 9-substituted 9-(2'-bromomethylphenyl)fluorene derivatives and compared their HNMR behavior with those of 9-substituted 9-(2'-methylphenyl)fluorene derivatives. The conclusions drawn from the study indicated that the conformational equilibria were influenced by electronic repulsion and/or steric hindrance between the 2'-bromomethyl group and the 9-carbonyl group or the fluorene ring. Chemicals used in the process included NBS (N-Bromosuccinimide), BPO (Benzoyl peroxide), carbon tetrachloride, dry hydrogen bromide, and various solvents such as CDCl3, DMSO-d6, acetone-d6, and methanol-d4 for NMR spectroscopy, as well as reagents for the synthesis and purification of the fluorene derivatives.

Post a RFQ

Cas No.:

Product Name:

Quantity:

Please select Metric Ton KG G Pound L ML

Email:

Company name:

Valid Period:

Detailed Requirements:

• Sample
• MOQ
• GMP
• FDA
• Price
  FOB CIF CFR EXW
• Urgent purchase

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

Remove

Submit

1

What can I do for you?
Get Best Price

Get Best Price for 811-98-3 METHANOL-D4

Send

Send

Metric Ton KG G Pound L ML

Send

Send