122898-71-9Relevant academic research and scientific papers
Oxidation of the perchlorotriphenylmethyl radical to the carbocation, and its unique abrupt reversion
Ballester, Manuel,Miravitlles, Carlos,Molins, Elies,Carreras, Conxita
, p. 2748 - 2751 (2003)
A solution of AlCl3 in CH2Cl2 reacts slowly, at room temperature, with perchlorotriphenylmethyl radical (PTM.), an inert carbon free radical, to give perchlorotriphenylmethyl cation (PTM+) quantitativ
Inert Carbon Free Radicals. 10. Chlorination of Perchlorotriphenylmethyl (PTM) Radical. Synthesis, Structure, and Reactivity of Perchloro(diphenylmethylene)cyclohexa-1,4-diene
Ballester, M.,Riera, J.,Castaner, J.,Carreras, C.,Ubierna, J. J.,et al.
, p. 4611 - 4615 (1989)
Perchlorotriphenylmethyl radical (PTM-radical) is the paradigm of the chlorine-shielded "inert free radicals" (IFRs), which owe their unique chemical inertia to the colossal overcrowding about their trivalent carbon.However, they are active in single elec
