Perfluorohexadecane

Base Information

• Chemical Name: Perfluorohexadecane
• CAS No.: 355-49-7
• Molecular Formula: C16F34
• Molecular Weight: 838.122
• Hs Code.: 2903399090
• European Community (EC) Number: 206-588-7
• DSSTox Substance ID: DTXSID40188997
• Nikkaji Number: J193.845B
• Wikidata: Q83060892
• Mol file: 355-49-7.mol

Synonyms:Perfluorohexadecane;355-49-7;Tetratriacontafluorohexadecane;1,1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,13,13,14,14,15,15,16,16,16-tetratriacontafluorohexadecane;EINECS 206-588-7;Hexadecane,1,1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,13,13,14,14,15,15,16,16,16-tetratriacontafluoro-;SCHEMBL984715;Hexadecane, tetratriacontafluoro-;DTXSID40188997;C16F34;MFCD00042085;AKOS016015565;C16-F34;FT-0723219;2-Aminomethyl-1-N-Fmoc-piperidinehydrochloride

Chemical Property of Perfluorohexadecane

Chemical Property:

• Vapor Pressure: 0.0179mmHg at 25°C
• Melting Point: 125-126°C
• Refractive Index: 1.269
• Boiling Point: 262.3 °C at 760 mmHg
• Flash Point: 113.8 °C
• PSA: 0.00000
• Density: 1.751 g/cm³
• LogP: 11.00520
• XLogP3: 11.8
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 34
• Rotatable Bond Count: 13
• Exact Mass: 837.9457075
• Heavy Atom Count: 50
• Complexity: 1140

Purity/Quality:

98%,99%, ^*data from raw suppliers

Perfluorohexadecane ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C(C(C(C(C(C(C(C(C(F)(F)F)(F)F)(F)F)(F)F)(F)F)(F)F)(F)F)(F)F)(C(C(C(C(C(C(C(F)(F)F)(F)F)(F)F)(F)F)(F)F)(F)F)(F)F)(F)F

Technology Process of Perfluorohexadecane

There total 28 articles about Perfluorohexadecane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

Perfluorazooctan (3829-39-8) → perfluorocetane (355-49-7)

Guidance literature:

In various solvent(s); for 7h; Mechanism; Quantum yield; Irradiation; var. wavelenght; also trans-cis isomerization;

DOI:10.1246/cl.1995.533

Reference yield: 71.0%

hydroperfluorooctane (335-65-9) → perfluorocetane (355-49-7) + Fluorosulfuric acid heptadecafluorooctyl ester (133559-42-9)

Guidance literature:

With sodium fluorosulfonate; fluorosulphonic acid; for 20h; electrolysis (Ti-cathode at 0.2 A);

DOI:10.1007/BF01184558

Reference yield: 70.0%

1-iodoheptadecafluorooctane (507-63-1) + allyl alcohol (107-18-6) → hydroperfluorooctane (335-65-9) + perfluorocetane (355-49-7) + (3-perfluoro-n-octyl)prop-2-enol (2340-84-3) + (2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9,9-heptadecafluorononyl)oxirane (38565-53-6)

Guidance literature:

With potassium hydroxide; 2,2'-azobis(isobutyronitrile); In 1,2-dichloro-ethane; at 70 ℃; for 2h;

DOI:10.1016/S0022-1139(00)00214-1

upstream raw materials:

Hexadecane

[1,3]-dioxolan-2-one

1-iodoheptadecafluorooctane

C₆F₁₃IZn

Downstream raw materials:

polytetrafluoroethylene

perfluoropropylene

octafluoro-1-butene

Octafluorocyclobutane

Refernces

• 1、 Nakamura, Takako,Koga, Yoshinori. "Perfluorooctylation of aromatic compounds with perfluoroazooctane upon 185 nm irradiation in a two-phase system". . p. 659 - 662. Retrieved 1998.
• 2、 -. "METHOD FOR PRODUCING TETRAFLUOROETHYLENE AND/OR HEXAFLUOROPROPYLENE". Paragraph 0051. . Retrieved 2016/11/09.
• 3、 Rubio,Blancou,Commeyras. "-". . p. 1 - 5. Retrieved 2007/10/03.