2,2,3,3,3-Pentafluoropropyl acrylate

Base Information

• Chemical Name: 2,2,3,3,3-Pentafluoropropyl acrylate
• CAS No.: 356-86-5
• Molecular Formula: C6H5 F5 O2
• Molecular Weight: 204.097
• Hs Code.: 29161290
• European Community (EC) Number: 206-608-4
• UNII: PE6QE9Q6K2
• DSSTox Substance ID: DTXSID9059884
• Nikkaji Number: J193.854A
• Wikidata: Q81985257
• Mol file: 356-86-5.mol

Synonyms:2,2,3,3,3-Pentafluoropropyl acrylate;356-86-5;1H,1H-Pentafluoropropyl acrylate;2,2,3,3,3-pentafluoropropyl prop-2-enoate;2-Propenoic acid, 2,2,3,3,3-pentafluoropropyl ester;2,2,3,3,3-PENTAFLUOROPROPYLACRYLATE;EINECS 206-608-4;2,2,3,3,3-Pentafluoropropyl Acrylate (stabilized with TBC);C6H5F5O2;PE6QE9Q6K2;SCHEMBL184088;1h,1h-perfluoropropyl acrylate;DTXSID9059884;MFCD00039257;AKOS015894280;FS-3901;2,2,3,3,3-Pentafluoropropyl 2-propenoate;FT-0609057;P2352;D92205;Acrylic acid=2,2,3,3,3-pentafluoropropyl ester;Acrylic Acid 2,2,3,3,3-Pentafluoropropyl Ester;1H,1H-Pentafluoropropyl acrylate contains 100 ppm 4-tert-butylcatechol as inhibitor;2,2,3,3,3-Pentafluoropropyl acrylate contains 100 ppm 4-tert-butylcatechol as inhibitor;2,2,3,3,3-Pentafluoropropyl acrylate, 98%, contains 100 ppm 4-tert-butylcatechol as inhibitor

Chemical Property of 2,2,3,3,3-Pentafluoropropyl acrylate

Chemical Property:

• Vapor Pressure: 34.8mmHg at 25°C
• Melting Point: 49-50°C
• Refractive Index: n20/D 1.336(lit.)
• Boiling Point: 50 °C100 mm Hg(lit.)
• Flash Point: 21.7°C
• PSA: 26.30000
• Density: 1.329g/cm³
• LogP: 1.91320
• Storage Temp.: Keep Cold
• XLogP3: 2.5
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 7
• Rotatable Bond Count: 4
• Exact Mass: 204.02097021
• Heavy Atom Count: 13
• Complexity: 208

Purity/Quality:

98%,99%, ^*data from raw suppliers

2,2,3,3,3-Pentafluoropropyl acrylate ^*data from reagent suppliers

Safty Information:

• Hazard Codes: Xn,F
• Statements: 10-20/21/22-36/37
• Safety Statements: 16-26-36

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C=CC(=O)OCC(C(F)(F)F)(F)F

Technology Process of 2,2,3,3,3-Pentafluoropropyl acrylate

There total 2 articles about 2,2,3,3,3-Pentafluoropropyl acrylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

2,2,3,3,3-pentafluoropropyl alcohol (422-05-9) + acrylic acid (79-10-7) → 2,2,3,3,3-pentafluoropropyl acrylate (356-86-5)

Guidance literature:

With hydroquinone; sulfuric acid; In dichloropentafluoropropane (R-225); at 0 - 45 ℃; for 21h; Heating / reflux;

Reference yield:

2,2,3,3,3-pentafluoropropyl alcohol (422-05-9) + acryloyl chloride (814-68-6,25189-84-8) → 2,2,3,3,3-pentafluoropropyl acrylate (356-86-5)

Guidance literature:

With quinoline; nitrobenzene;

DOI:10.1002/pol.1955.120158018

Reference yield: 80.0%

2,2,3,3,3-pentafluoropropyl acrylate (356-86-5) + 2',5'-dimethoxyacetophenone (1201-38-3) → 2,2,3,3,3-pentafluoropropyl (E)-3-(2-acetyl-3,6-dimethoxyphenyl)acrylate

Guidance literature:

With silver hexafluoroantimonate; dichloro(pentamethylcyclopentadienyl)rhodium (III) dimer; copper(II) acetate monohydrate; In tert-Amyl alcohol; at 20 - 100 ℃; for 12.33h; regioselective reaction; Schlenk technique; Sealed tube;

DOI:10.1002/ejoc.201402904

upstream raw materials:

2,2,3,3,3-pentafluoropropyl alcohol

acryloyl chloride

acrylic acid

Refernces