N-(o-Tolyl)-sydnon

Base Information

Chemical Name:N-(o-Tolyl)-sydnon
CAS No.:3483-18-9
Molecular Formula:C9H8N2O2
Molecular Weight:176.175
Hs Code.:2934999090
DSSTox Substance ID:DTXSID40188371
Mol file:3483-18-9.mol

Synonyms:3-(o-Tolyl)sydnone;N-(o-Tolyl)-sydnon;Sydnone, 3-o-tolyl-;3-(2-Methylphenyl)sydnone;BRN 3672322;Sydnone, 3-(2-methylphenyl)-;3483-18-9;1,2,3-Oxadiazolium, 5-hydroxy-3-(2-methylphenyl)-, inner salt;1,2,3-Oxadiazolium, 5-hydroxy-3-(2-methylphenyl)-, inner salt (9CI);N-tolylsydnon;DTXSID40188371;AKOS024327453;LS-148436

Suppliers and Price of N-(o-Tolyl)-sydnon

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 4 raw suppliers

Chemical Property of N-(o-Tolyl)-sydnon

Chemical Property:

Boiling Point:°Cat760mmHg
Flash Point:°C
PSA：48.03000
Density:g/cm³
LogP:1.13390
XLogP3:3.2
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:1
Exact Mass:176.058577502
Heavy Atom Count:13
Complexity:177

Purity/Quality:: 95% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC1=CC=CC=C1[N+]2=NOC(=C2)[O-]

Technology Process of N-(o-Tolyl)-sydnon

There total 5 articles about N-(o-Tolyl)-sydnon which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

: 21911-61-5
N-(2-methylphenyl)glycine

: 3483-18-9
3-o-tolyl-sydnone

Guidance literature:: With N,N,N’,N’-tetrabromobenzene-1,3-disulfonamide; acetic anhydride; sodium nitrite; In dichloromethane; at 0 - 5 ℃; for 7h;
DOI:10.3987/COM-06-10859

Reference yield: 80.0%

: 90557-96-3
N-nitroso-N-o-tolyl-glycine

: 3483-18-9
3-o-tolyl-sydnone

Guidance literature:: With 1,3-dibromo-5,5-dimethylimidazolidine-2,4-dione; In dichloromethane; at 0 - 5 ℃; for 4h;
DOI:10.3987/COM-05-10574

Reference yield:

: 95-53-4
o-toluidine

: 3483-18-9
3-o-tolyl-sydnone

Guidance literature:: Multi-step reaction with 3 steps

1.1: SiO₂ / 0.13 h / 20 °C / microwave irradiation

1.2: 85 percent / aq. sodium hydroxide / ethanol / 0.17 h / Heating

2.1: 92 percent / silica chloride; wet SiO₂; sodium nitrite / CH₂Cl₂ / 2 h / 0 - 5 °C

3.1: 80 percent / 1,3-dibromo-5,5-dimethylhydantoin / CH₂Cl₂ / 4 h / 0 - 5 °C

With tetrachlorosilane; 1,3-dibromo-5,5-dimethylimidazolidine-2,4-dione; silica gel; sodium nitrite; In dichloromethane;
DOI:10.3987/COM-05-10574