Hexanal methylformylhydrazone

Base Information

• Chemical Name: Hexanal methylformylhydrazone
• CAS No.: 57590-22-4
• Molecular Formula: C8H16N2O
• Molecular Weight: 156.23
• NSC Number: 272568
• Mol file: 57590-22-4.mol

Synonyms:hexanal methylformylhydrazone;HMFH

Chemical Property of Hexanal methylformylhydrazone

Chemical Property:

• Boiling Point: 222.4°Cat760mmHg
• Flash Point: 88.3°C
• PSA: 32.67000
• Density: 0.9g/cm³
• LogP: 2.27660
• XLogP3: 1.6
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 5
• Exact Mass: 156.126263138
• Heavy Atom Count: 11
• Complexity: 123

Purity/Quality:

99% ^*data from raw suppliers

HEXANALMETHYLFORMYLHYDRAZONE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: CCCCCC=NN(C)C=O
• Isomeric SMILES: CCCCC/C=N/N(C)C=O

Technology Process of Hexanal methylformylhydrazone

There total 4 articles about Hexanal methylformylhydrazone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

acetic acid hydrazide (1068-57-1) + hexanal (66-25-1) → Capronaldehyd-acetyl-hydrazon (57590-22-4)

Guidance literature:

In hexane; at 20 ℃; for 2h; Inert atmosphere;

DOI:10.1016/j.tetlet.2014.09.088

Reference yield:

geralcin E (24397-78-2) → Capronaldehyd-acetyl-hydrazon (57590-22-4)

Guidance literature:

With sodium hydroxide; In methanol;

DOI:10.1021/ja01038a081

Reference yield:

1-Methyl-1-formylhydrazid (758-17-8) + hexanal (66-25-1) → Hexanal-N-methyl-N-formyl-hydrazon (57590-22-4)

Guidance literature:

upstream raw materials:

1-Methyl-1-formylhydrazid

hexanal

geralcin E

acetic acid hydrazide

Refernces

• 1、 Tello-Aburto, Rodolfo,Lucero, Alyssa N.,Rogelj, Snezna. "A catalytic approach to the MH-031 lactone: Application to the synthesis of geralcin analogs". supporting information. p. 6266 - 6268. Retrieved 2014/12/11.