Butylamine, N-benzylidene-

Base Information

• Chemical Name: Butylamine, N-benzylidene-
• CAS No.: 1077-18-5
• Molecular Formula: C11H15 N
• Molecular Weight: 161.247
• NSC Number: 165808
• DSSTox Substance ID: DTXSID90304443
• Nikkaji Number: J123.415C,J2.048.144G
• Mol file: 1077-18-5.mol

Synonyms:1077-18-5;N-butyl-1-phenylmethanimine;n-benzylidene butylamine;Butylamine, N-benzylidene-;N-Benzylidenebutylamine;Butylbenzylideneamine;1-Butanamine, N-(phenylmethylene)-;(E)-N-benzylidenebutan-1-amine;N-[(E)-Phenylmethylidene]-1-butanamine;Benzylidene-(butylamine);N-Benzylidene-n-butylamine;N-[Phenylmethylidene]-1-butanamine #;Benzylidenbutylamin;NSC165808;Benzylidene-butyl-amine;N-Benzyldene butylamine;N-butyl-1-phenyl-methanimine;SCHEMBL1323649;DTXSID90304443;(E)-butyl(phenylmethylidene)amine;IADUISXJUXDNFB-ZRDIBKRKSA-N;AKOS006283313;AKOS024332541;NSC-165808;AS-82313;FT-0654889;E77652;A801748

Chemical Property of Butylamine, N-benzylidene-

Chemical Property:

• Vapor Pressure: 0.048mmHg at 25°C
• Boiling Point: 244.2°Cat760mmHg
• PKA: 5.37±0.50(Predicted)
• Flash Point: 93.1°C
• PSA: 12.36000
• Density: 0.87g/cm³
• LogP: 2.90560
• XLogP3: 2.7
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 4
• Exact Mass: 161.120449483
• Heavy Atom Count: 12
• Complexity: 123

Purity/Quality:

98%,99%, ^*data from raw suppliers

N-BENZYLIDENE BUTYLAMINE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCCCN=CC1=CC=CC=C1

Technology Process of Butylamine, N-benzylidene-

There total 46 articles about Butylamine, N-benzylidene- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

benzaldehyde (100-52-7) + N-butylamine (109-73-9,85404-21-3) → N-benzylidenebutan-1-amine (1077-18-5)

Guidance literature:

With aluminum oxide; for 5h; Milling;

DOI:10.1055/s-0039-1691599

Reference yield: 96.8%

benzonitrile (100-47-0) + N-butylamine (109-73-9,85404-21-3) → N-benzylidene benzylamine (780-25-6) + N-benzylidenebutan-1-amine (1077-18-5)

Guidance literature:

With ammonium hydroxide; hydrogen; In hexane; at 80 ℃; for 4h; under 750.075 Torr; Autoclave; Green chemistry;

DOI:10.1021/acscatal.9b01597

Reference yield: 96.0%

N-butylamine (109-73-9,85404-21-3) + benzyl alcohol (100-51-6,185532-71-2) → N-benzylidenebutan-1-amine (1077-18-5)

Guidance literature:

With oxygen; In toluene; at 80 ℃; for 24h; Schlenk technique;

upstream raw materials:

benzaldehyde

N-butylamine

N-butyl-benzimidoyl chloride

[(Z)-Butylimino]-phenyl-acetic acid

Downstream raw materials:

2-phenylphenanthro[9,10-d]oxazole

3-Butyl-2-phenyl-1,3-thiazolidin-4-one

Butyl-((3E,6Z)-1-phenyl-nona-3,6,8-trienyl)-amine

1-phenyl-2-nitroprop-1-ene

Refernces

• 1、 Marwaha, Alka,Singh, Parvesh,Mahajan, Mohinder P.. "An in-depth analysis of the effect of substituents on imines in cycloaddition reactions with nitrosoalkenes". . p. 5474 - 5486. Retrieved 2006.
• 2、 Zhong, Mingdong,Liu, Ying,Liu, Xin,Ma, Xiaoli,Yang, Zhi. "Synthesis of [LAl(μ-S)2AlL] (L?=?HC(CMeNAr)2, Ar?=?2,6-Et2C6H3) with the insertion of sulfur into the Al–H bonds of LAlH2 and its application in catalysis". . p. 182 - 185. Retrieved 2017.
• 3、 Ding, Yi,Ma, Xiaoli,Liu, Yashuai,Liu, Wenqing,Ni, Congjian,Yan, Ben,Yan, Li,Yang, Zhi. "Synthesis of organoaluminum chalcogenides and their applications in Lewis acid catalysis". . . Retrieved 2019.
• 4、 Jiang, Lan,Jin, Luolu,Tian, Haiwen,Yuan, Xueqin,Yu, Xiaochun,Xu, Qing. "Direct and mild palladium-catalyzed aerobic oxidative synthesis of imines from alcohols and amines under ambient conditions". . p. 10833 - 10835. Retrieved 2011.
• 5、 Xu, Jian,Zhuang, Rongqiang,Bao, Lingling,Tang, Guo,Zhao, Yufen. "KOH-mediated transition metal-free synthesis of imines from alcohols and amines". . p. 2384 - 2387. Retrieved 2012.
• 6、 Deng, Wei,Fan, Xiao-Nan,Ou, Hui-Dan,Yao, Zi-Jian. "Air-Stable Half-Sandwich Iridium Complexes as Aerobic Oxidation Catalysts for Imine Synthesis". . . Retrieved 2020.
• 7、 Yu, Bo,Yang, Ke-Fang,Bai, Xing-Feng,Cao, Jian,Zheng, Zhan-Jiang,Cui, Yu-Ming,Xu, Zheng,Li, Li,Xu, Li-Wen. "Ligand-Controlled Inversion of Diastereo- and Enantioselectivity in Silver-Catalyzed Azomethine Ylide-Imine Cycloaddition of Glycine Aldimino Esters with Imines". . p. 2551 - 2554. Retrieved 2018.
• 8、 Ogata,Kawasaki. "-". . p. 325,326. Retrieved 1971.
• 9、 Ghosh, Payel,Mondal, Susmita,Hajra, Alakananda. "Tert-Butyl Hydroperoxide-Mediated Oxo-Sulfonylation of 2 H-Indazoles with Sulfinic Acid toward Indazol-3(2 H)-ones". . p. 1086 - 1090. Retrieved 2020.
• 10、 Li, Yue,Xiao, Kang,Li, Jingjing,Jiang, Pingping,Jiang, Yuchen,Du, Shengyu,Leng, Yan. "Molybdenum Nitride Nanocatalyst Derived from Melamine and Polyoxometalate-based Hybrid for Oxidative Coupling of Amines to Imines with Air". . p. 4317 - 4323. Retrieved 2018.