Chloro-tris(2,3,4,5,6-pentafluorophenyl)stannane

Base Information

• Chemical Name: Chloro-tris(2,3,4,5,6-pentafluorophenyl)stannane
• CAS No.: 1755-63-1
• Molecular Formula: C18ClF15Sn
• Molecular Weight: 655.337
• NSC Number: 179743
• DSSTox Substance ID: DTXSID50306781
• Wikidata: Q82054060
• Mol file: 1755-63-1.mol

Synonyms:1755-63-1;chloro-tris(2,3,4,5,6-pentafluorophenyl)stannane;NSC179743;DTXSID50306781;NSC-179743

Chemical Property of Chloro-tris(2,3,4,5,6-pentafluorophenyl)stannane

Chemical Property:

• Vapor Pressure: 6.31E-06mmHg at 25°C
• Boiling Point: 389.6°C at 760 mmHg
• Flash Point: 189.4°C
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 15
• Rotatable Bond Count: 3
• Exact Mass: 655.847103
• Heavy Atom Count: 35
• Complexity: 612

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: C1(=C(C(=C(C(=C1F)F)[Sn](C2=C(C(=C(C(=C2F)F)F)F)F)(C3=C(C(=C(C(=C3F)F)F)F)F)Cl)F)F)F

Technology Process of Chloro-tris(2,3,4,5,6-pentafluorophenyl)stannane

There total 10 articles about Chloro-tris(2,3,4,5,6-pentafluorophenyl)stannane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

hydrogenchloride (7647-01-0,15364-23-5) + (C6F5)3Sn(CH2CHCH2) → tris-(pentafluoro phenyl) chloro stannane (1755-63-1)

Guidance literature:

In tetrachloromethane; Ar-atmosphere; bubbling dry HCl gas through soln. of Sn-compd. for 4 h under reflux; evapn., recrystn. (petroleum ether);

DOI:10.1016/S0022-328X(98)00928-0

Reference yield: 84.0%

tin(IV) chloride (7646-78-8) + perfluoro(tetraphenyl)tin (1065-49-2) → tris-(pentafluoro phenyl) chloro stannane (1755-63-1)

Guidance literature:

In neat (no solvent); (Ar, Schlenk technique); stirring stoich. mixt. of tin compds. at room temp. for 48 h; addn. of toluene, evapn., elem. anal.;

DOI:10.1016/j.jorganchem.2010.07.019

Reference yield: 75.0%

hydrogenchloride (7647-01-0,15364-23-5) + tris-(pentafluoro phenyl) p-tolyl stannane (1064-89-7) → tris-(pentafluoro phenyl) chloro stannane (1755-63-1)

Guidance literature:

In neat (no solvent); heating in a closed tube at 100°C, 17 hours;;

upstream raw materials:

hydrogenchloride

tin(IV) chloride

perfluoro(tetraphenyl)tin

bis-{tris-(pentafluoro phenyl) stannyl} mercury

Downstream raw materials:

tris-(pentafluoro phenyl) hydroxo stannane

bis-(pentafluoro phenyl) tin bis-(8-hydroxy quinolate)

bis-{tris-(pentafluoro phenyl)} distannoxane

hexakis-(pentafluoro phenyl) distannane