Molybdenum,bis[(1,2,3,4,5,6-eta)-methylbenzene]-

Base Information

Chemical Name:Molybdenum,bis[(1,2,3,4,5,6-eta)-methylbenzene]-
CAS No.:12131-22-5
Molecular Formula:C14H16 Mo
Molecular Weight:280.221
Hs Code.:

Synonyms:Molybdenum,bis[(1,2,3,4,5,6-.eta.)-methylbenzene]-;DWPKMPZFZNWNTN-UHFFFAOYSA-N;12131-22-5;Molybdenum, bis((1,2,3,4,5,6-eta6)-methylbenzene)-;Molybdenum,bis[(1,2,3,4,5,6-.eta.<6>)-methylbenzene]-;Molybdenum,bis[(1,2,3,4,5,6-.eta.6)-methylbenzene]-

Suppliers and Price of Molybdenum,bis[(1,2,3,4,5,6-eta)-methylbenzene]-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of Molybdenum,bis[(1,2,3,4,5,6-eta)-methylbenzene]-

Chemical Property:

Vapor Pressure:27.7mmHg at 25°C
Boiling Point:110.6°Cat760mmHg
Flash Point:10°C
Density:g/cm³
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:6
Rotatable Bond Count:0
Exact Mass:282.030604
Heavy Atom Count:15
Complexity:191

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C[C-]1[CH-][CH-][CH-][CH-][CH-]1.CC1=CC=CC=C1.[Mo]

Technology Process of Molybdenum,bis[(1,2,3,4,5,6-eta)-methylbenzene]-

There total 8 articles about Molybdenum,bis[(1,2,3,4,5,6-eta)-methylbenzene]- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 71.8%

: 10241-05-1
molybdenum(V) chloride

: 108-88-3,15644-74-3,16713-13-6
toluene

: 7429-90-5
aluminium

: 12131-22-5
bis(η6-toluene)molybdenium(0)

Guidance literature:: With AlCl₃; In toluene; Ar-atmosphere; succesive addn. of AlCl3, Al-dust and toluene to MoCl5, stirring and refluxing for 40 h, cooling to 40°C, slow addn. of THF, refluxing for 18 h; cooling, filtration, evapn. of filtrate (0.1 Pa), extn. into boiling pentane, filtration, concn., crystn. on cooling to -78°C, decantation, drying (vac.);
DOI:10.1039/DT9950001563

Reference yield: 41.0%

: 52346-34-6
bis(η-chlorobenzene)molybdenum

: 676-58-4
methylmagnesium chloride

: 12131-22-5
bis(η6-toluene)molybdenium(0)

Guidance literature:: In tetrahydrofuran; diethyl ether; Ar; Mo-compound in THF was treated with CH3MgCl in Et2O at room temp.; protected from light and left for 5 d; volatile components removed under reduced pressure; extd. (petroleum ether); filtered; concd.; cooled to -78°C; collected; dried in vacuo;
DOI:10.1016/S0022-328X(00)99703-1

Reference yield: 39.0%

: 10241-05-1
molybdenum(V) chloride

: 108-88-3,15644-74-3,16713-13-6
toluene

: 12131-22-5
bis(η6-toluene)molybdenium(0)

Guidance literature:: With Al; AlCl₃; In toluene; stirring mixt. of MoCl5, Al and AlCl3 in toluene for 30 h at the boiling point of the mixt., under purified Ar atmosphere; treating with THF at room temp.; refluxing for 8 h; mechanism discussed;; filtration; evapn. to dryness; treating residue with heptane; filtration; washing carefully with heptane until washing is colorless; cooling to -78°C; drying in vac. at room temp.; sublimation at 100°C and 0.01 Torr; elem. anal.;;