(Z)-Diisopropyldiazene

Base Information

• Chemical Name: (Z)-Diisopropyldiazene
• CAS No.: 23201-84-5
• Molecular Formula: C6H14 N2
• Molecular Weight: 114.191
• UNII: 71TGE6716F
• Nikkaji Number: J43.490F,J2.690.708J,J2.690.709H
• Mol file: 23201-84-5.mol

Synonyms:2,2'-Azobispropane;(Z)-Diisopropyldiazene;Diisopropyldiazene;Diisopropyl diazene, trans-;71TGE6716F;3880-49-7;Azoisopropane;Azoethane, 1,1'-dimethyl-;Diazene, bis(1-methylethyl)-;Diazene, diisopropyl;1,2-Diisopropyldiazene;2,2'-AZOISOPROPANE;SCHEMBL491681;UNII-71TGE6716F;(Z)-iso-(C3H7)2NN;SCHEMBL13006360;BXCOOPLIKAAONJ-UHFFFAOYSA-N;PROPANE, 2,2'-AZOBIS-;AKOS015960799;1,2-BIS(1-METHYLETHYL)DIAZENE;23201-84-5;DIAZENE, 1,2-BIS(1-METHYLETHYL)-

Chemical Property of (Z)-Diisopropyldiazene

Chemical Property:

• XLogP3: 1.8
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 2
• Exact Mass: 114.115698455
• Heavy Atom Count: 8
• Complexity: 64.6

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC(C)N=NC(C)C

Technology Process of (Z)-Diisopropyldiazene

There total 5 articles about (Z)-Diisopropyldiazene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

2,3-Dimethyl-2-butene (563-79-1) + azobisisopropane (15464-00-3) → 2,3-dimethyl-2,3-epoxybutane (5076-20-0) + propan-1-ol (71-23-8) + 2-hydroperoxypropane (3031-75-2) + (Z)-1,1'-dimethylazoethane (23201-84-5) + acetone (67-64-1)

Guidance literature:

With oxygen; at 29.9 - 134.9 ℃; for 0.5h; Thermodynamic data; Kinetics; Mechanism; Arrhenius parameters;

Reference yield:

azobisisopropane (15464-00-3) → propene (187737-37-7,13987-01-4,15220-87-8,9003-07-0,676-63-1,25085-53-4) + propane (74-98-6) + 2,3-dimethylbutane (79-29-8) + (Z)-1,1'-dimethylazoethane (23201-84-5)

Guidance literature:

at 59.9 - 99.9 ℃; under 5 Torr; Rate constant; Irradiation; nitrogen atmosphere, 495 Torr;

DOI:10.1039/f19827802535

Reference yield:

azobisisopropane (15464-00-3) → 2,3-dimethylbutane (79-29-8) + 2-hydroperoxypropane (3031-75-2) + di-i-propyl peroxide (16642-57-2) + (Z)-1,1'-dimethylazoethane (23201-84-5) + isopropyl alcohol (67-63-0,8013-70-5) + acetone (67-64-1)

Guidance literature:

With oxygen; In decane; at -20.1 - 49.9 ℃; for 30h; Product distribution; Mechanism; Irradiation; photolysis in absence of O₂ and with varied initial O₂ conc.; effect of temperature;

DOI:10.1039/f19878302433

upstream raw materials:

2,3-Dimethyl-2-butene

azobisisopropane

Downstream raw materials:

C₃₅H₅₈N₆O₄