Molybdenum, pentacarbonyl(triphenylarsine)-

Base Information

Chemical Name:Molybdenum, pentacarbonyl(triphenylarsine)-
CAS No.:19212-22-7
Molecular Formula:C₂₃H₁₅AsMoO₅
Molecular Weight:542.231
Hs Code.:
NSC Number:168773

Synonyms:19212-22-7;Molybdenum, pentacarbonyl(triphenylarsine)-;ANTINEOPLASTIC-168773;NSC168773;NSC 168773;NSC-168773

Suppliers and Price of Molybdenum, pentacarbonyl(triphenylarsine)-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
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price

Total 1 raw suppliers

Chemical Property of Molybdenum, pentacarbonyl(triphenylarsine)-

Chemical Property:

Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:5
Rotatable Bond Count:3
Exact Mass:544.926772
Heavy Atom Count:30
Complexity:407

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].C1=CC=C(C=C1)[AsH](C2=CC=CC=C2)C3=CC=CC=C3.[Mo]

Technology Process of Molybdenum, pentacarbonyl(triphenylarsine)-

There total 2 articles about Molybdenum, pentacarbonyl(triphenylarsine)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 603-32-7
triphenyl-arsane

: 13939-06-5,199620-15-0
molybdenum hexacarbonyl

: 19212-22-7
Mo(CO)5(As(C₆H₅)3)

Guidance literature:: In cyclohexane; Irradiation (UV/VIS); under Ar, irradn. of Mo complex in presence of ligand; not isolated, detected by IR;
DOI:10.1021/ja00357a012

Reference yield:

: 603-32-7
triphenyl-arsane

: 13939-06-5,199620-15-0
molybdenum hexacarbonyl

: 16742-97-5,252765-83-6,87680-69-1
cis-{molybdenum⁽⁰⁾(carbonyl)4(As(phenyl)3)2}

: 19212-22-7
Mo(CO)5(As(C₆H₅)3)

Guidance literature:: With THF; In tetrahydrofuran; Irradiation (UV/VIS); N2-atmosphere; photolysis of hexacaronyl, addn. of ligand; evapn., sublimation off of unreacted hexacarbonyl (60°C, vac.), washing (cold hexane), chromy. (SiO2, hexane), recrystn. (hexane);
DOI:10.1039/DT9940002827

Reference yield:

: 19212-22-7
Mo(CO)5(As(C₆H₅)3)

: 1184-78-7
trimethylamine-N-oxide

: 603-32-7
triphenyl-arsane

: 16742-97-5,252765-83-6,87680-69-1
cis-{molybdenum⁽⁰⁾(carbonyl)4(As(phenyl)3)2}

: 124-38-9,18923-20-1
carbon dioxide

: 75-50-3
trimethylamine

Guidance literature:: In dichloromethane; acetonitrile; 26°C, CH2Cl2/CH3CN (1:1 v/v) soln.; progress of reaction monitored by IR spectroscopy; Kinetics;