N,N-Diphenylhydroxylamine

Base Information

• Chemical Name: N,N-Diphenylhydroxylamine
• CAS No.: 1079-64-7
• Molecular Formula: C12H11 N O
• Molecular Weight: 185.225
• DSSTox Substance ID: DTXSID70148322
• Wikidata: Q83013838
• Mol file: 1079-64-7.mol

Synonyms:N,N-Diphenylhydroxylamine;Benzenamine, N-hydroxy-N-phenyl-;1079-64-7;hydroxydiphenylamine;Diphenyl Nitroxide Discontinued;SCHEMBL1032263;DTXSID70148322

Chemical Property of N,N-Diphenylhydroxylamine

Chemical Property:

• Vapor Pressure: 0.000387mmHg at 25°C
• Boiling Point: 304.3°Cat760mmHg
• Flash Point: 151.2°C
• Density: 1.194g/cm³
• XLogP3: 3.4
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 2
• Exact Mass: 185.084063974
• Heavy Atom Count: 14
• Complexity: 142

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C(C=C1)N(C2=CC=CC=C2)O

Technology Process of N,N-Diphenylhydroxylamine

There total 5 articles about N,N-Diphenylhydroxylamine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

diphenylamine (122-39-4) → N,N-diphenylhydroxylamine (1079-64-7)

Guidance literature:

With sodium perborate; sodium molybdate tetrahydrate; In acetic acid; at 50 ℃; for 1h; Temperature; Kinetics; Thermodynamic data; Catalytic behavior;

DOI:10.1007/s11696-018-0599-z

Reference yield:

triheptyl-amine oxide (118981-85-4) → 1-Heptene (592-76-7) + N,N-diphenylhydroxylamine (1079-64-7)

Guidance literature:

beim Erhitzen unter vermindertem Druck;

DOI:10.1021/ja01561a050

Reference yield:

phenylmagnesium bromide → N,N-diphenylhydroxylamine (1079-64-7)

Guidance literature:

With N-nitrosodiphenylamine; In tetrahydrofuran; at -15 - 20 ℃; for 1.5h;

DOI:10.1080/00397919208021294

upstream raw materials:

triheptyl-amine oxide

Nitrosobenzene

diphenylamine

Downstream raw materials:

biphenyl

diphenylamine

O,O'-but-2-en-1,4-diyl-bis(N,N-diphenylhydroxylamine)

9H-carbazole

Refernces

• 1、 Karunakaran,Venkataramanan. "Conversion of anilines into azobenzenes in acetic acid with perborate and Mo(VI): correlation of reactivities". . p. 375 - 385. Retrieved 2019/02/14.
• 2、 Cardellini,Greci,Tosi. "Reactions of N-nitrosodiphenylamine with Grignard reagents. A convenient synthesis of diaryl- and dialkyl nitroxyls". . p. 201 - 207. Retrieved 2007/10/02.