Chlorimide

Base Information

• Chemical Name: Chlorimide
• CAS No.: 3400-09-7
• Molecular Formula: Cl2H N
• Molecular Weight: 85.9206
• UNII: KGU33GRT44
• DSSTox Substance ID: DTXSID4074936
• Nikkaji Number: J1.454.907B
• Wikipedia: Dichloramine
• Wikidata: Q905694
• Mol file: 3400-09-7.mol

Synonyms:Chlorimide;Dichloroamine;Dichloramine;3400-09-7;KGU33GRT44;iminochloride;imino chloride;NHCl2;UNII-KGU33GRT44;DTXSID4074936;LS-53012;Q905694

Chemical Property of Chlorimide

Chemical Property:

• Boiling Point: 115-117 °C(Press: 15 Torr)
• PKA: -11.14±0.70(Predicted)
• PSA: 12.03000
• Density: 1.429g/cm³
• LogP: 1.27450
• XLogP3: 1.4
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 0
• Exact Mass: 84.9486044
• Heavy Atom Count: 3
• Complexity: 2.8

Purity/Quality:

99%, ^*data from raw suppliers

DICHLORAMINE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: N(Cl)Cl

Technology Process of Chlorimide

There total 26 articles about Chlorimide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

ammonium chloride + chlorine (7782-50-5) → dichloroamine (3400-09-7) + nitrogen trichloride (10025-85-1)

Guidance literature:

In water;

Reference yield:

hydrogenchloride (7647-01-0,15364-23-5) + perchloric acid (7601-90-3) → dichloroamine (3400-09-7) + nitrogen trichloride (10025-85-1) + Ammonium

Guidance literature:

With sodium perchlorate; In water; NH2Cl soln. was added to cation-exchange column in H(1+) form (acidified with 3 M HCl, equilibrated with 0.1 M HClO4 and 0.1 M NaClO4, rinsed with water until neutral pH), eluted with water; monitored spectrophotometrically;

Reference yield:

Ammonium + chlorine (7782-50-5) → dichloroamine (3400-09-7) + nitrogen trichloride (10025-85-1)

Guidance literature:

In water; passing Cl2 into aq. NH4(1+)-salt soln. at pH < 4.4;;

DOI:10.1021/ja01354a011

upstream raw materials:

ammonium sulfate

sodium hypochlorite

chlorine

nitrogen trichloride

Downstream raw materials:

bromine

hydrogenchloride

nitrogen

hypochloric acid

Refernces

• 1、 -. "AQUEOUS SOLUTIONS CONTAINING CHLORAMINE WHICH ARE FREE FROM DI-AND TRICHLOROAMINE, AS WELL AS FROM AMMONIA". Page/Page column 3-4. . Retrieved 2008/12/04.
• 2、 Piela, Barbara,Wrona, Piotr K.. "Electrochemical behavior of chloramines on the rotating platinum and gold electrodes". . p. E255-E265. Retrieved 2008/10/08.