Capillone

Base Information

• Chemical Name: Capillone
• CAS No.: 74743-50-3
• Molecular Formula: C₁₂H₁₂O
• Molecular Weight: 172.227
• Mol file: 74743-50-3.mol

Synonyms:Sorbophenon;1-Phenyl-2,4-hexadien-1-on;Capillone;1-Phenyl-2,4-hexadiene-1-one;1-phenyl-2,4-hexendien-1-one;

Chemical Property of Capillone

Chemical Property:

• PSA: 17.07000
• LogP: 3.00160

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Capillone

There total 6 articles about Capillone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

α-bromoacetophenone (70-11-1) + crotonaldehyde (123-73-9,4170-30-3) → 1-phenyl-2,4-hexendien-1-one (112708-70-0,74743-50-3,5736-28-7)

Guidance literature:

With cerium(III) triiodide; In tetrahydrofuran; for 1h; Ambient temperature;

DOI:10.1039/c39850000777

Reference yield: 95.0%

trans-Crotonaldehyde (123-73-9,4170-30-3) + α-bromoacetophenone (70-11-1) → 1-phenyl-2,4-hexendien-1-one (112708-70-0,74743-50-3,5736-28-7)

Guidance literature:

With cerium(III) triiodide; In tetrahydrofuran; for 1h; Ambient temperature;

Reference yield:

acetophenone (98-86-2) + crotonaldehyde (123-73-9,4170-30-3) → 1-phenyl-2,4-hexendien-1-one (112708-70-0,74743-50-3,5736-28-7)

Guidance literature:

With (2,4,6-trimethyl-phenoxy)-magnesium bromide; In benzene; Heating;

upstream raw materials:

3-(diethylamino)-1-phenylprop-2-en-1-one

1-propenylmagnesium bromide

trans-Crotonaldehyde

α-bromoacetophenone

Downstream raw materials:

C₁₉H₂₂O

(E)-1-phenylhex-4-ene-1-one

1-Phenyl-4-hexen-1-ol

(E)-1-Phenyl-3-hexen-1-ol

Refernces

• 1、 Zhang, Li-Jun,Huang, Yao-Zeng. "On tertiary stibine I. Reaction of ω-bromoacetophenone with aldehydes mediated by diphenylantimonyorganometallic reagents". . p. 101 - 103. Retrieved 2007/10/02.
• 2、 Fukuzawa, Shin-ichi,Fujinami, Tatsuo,Sakai, Shizuyoshi. "Carbon-Carbon Bond Formation between α-Halogenoketones and Aldehydes Promoted by Cerium(III) Iodide or Cerium(III) Chloride-Sodium Iodide". . p. 777 - 778. Retrieved 2007/10/02.