Methyl Alpha-D-Arabinofuranoside

Base Information

• Chemical Name: Methyl Alpha-D-Arabinofuranoside
• CAS No.: 56607-40-0
• Molecular Formula: C6H12 O5
• Molecular Weight: 164.158
• Nikkaji Number: J635.650H
• Wikidata: Q27458119
• Mol file: 56607-40-0.mol

Synonyms:Methyl Alpha-D-Arabinofuranoside;56607-40-0;METHYL A-D-ARABINOFURANOSIDE;(2R,3S,4S,5S)-2-(HYDROXYMETHYL)-5-METHOXYOXOLANE-3,4-DIOL;(2R,3S,4S,5S)-2-(hydroxymethyl)-5-methoxytetrahydrofuran-3,4-diol;ALPHA-D-ARABINOFURANOSIDE, METHYL;MFCD18643081;AXR;Methyl -D-arabinofuranoside;QSPL 060;SCHEMBL1028044;AKOS006373043;s12200;BS-29091;W-203133;Q27458119

Chemical Property of Methyl Alpha-D-Arabinofuranoside

Chemical Property:

• Melting Point: 65-67 °C(Solv: ethyl acetate (141-78-6))
• Boiling Point: 348.7°Cat760mmHg
• PKA: 13.14±0.70(Predicted)
• Flash Point: 164.7°C
• PSA: 79.15000
• Density: 1.4g/cm³
• LogP: -1.92820
• XLogP3: -1.6
• Hydrogen Bond Donor Count: 3
• Hydrogen Bond Acceptor Count: 5
• Rotatable Bond Count: 2
• Exact Mass: 164.06847348
• Heavy Atom Count: 11
• Complexity: 128

Purity/Quality:

99% ^*data from raw suppliers

Methyl a-D-arabinofuranoside ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: COC1C(C(C(O1)CO)O)O
• Isomeric SMILES: CO[C@@H]1[C@H]([C@@H]([C@H](O1)CO)O)O

Technology Process of Methyl Alpha-D-Arabinofuranoside

There total 51 articles about Methyl Alpha-D-Arabinofuranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

methanol (67-56-1) + D-Ribose (532-20-7,613-83-2,7261-25-8,7687-39-0,13221-22-2,14795-83-6,15761-67-8,20074-49-1,25545-03-3,25545-04-4,32445-75-3,34436-17-4,36441-93-7,36468-53-8,37110-85-3,37388-49-1,38029-69-5,40461-77-6,40461-89-0,41546-19-4,41546-20-7,41546-21-8,41546-26-3,41546-29-6,41546-30-9,41546-31-0,126872-16-0,131064-98-7) → methyl ribofuranoside (1824-96-0,1824-97-1,3795-68-4,3795-69-5,4229-54-3,5531-18-0,7473-45-2,13039-63-9,13039-64-0,13039-65-1,13039-67-3,22416-73-5,22861-09-2,25129-51-5,52485-92-4,52689-55-1,52689-56-2,56607-40-0,72880-70-7,79083-42-4,86782-30-1,86782-31-2,89615-03-2,89673-67-6,89707-99-3,102045-32-9,135910-17-7)

Guidance literature:

With Dowex-50 (H+); at 4 ℃;

DOI:10.1002/ejoc.200600182

Reference yield: 100.0%

methanol (67-56-1) + D-ribose (50-69-1) → methyl ribofuranoside (1824-96-0,1824-97-1,3795-68-4,3795-69-5,4229-54-3,5531-18-0,7473-45-2,13039-63-9,13039-64-0,13039-65-1,13039-67-3,22416-73-5,22861-09-2,25129-51-5,52485-92-4,52689-55-1,52689-56-2,56607-40-0,72880-70-7,79083-42-4,86782-30-1,86782-31-2,89615-03-2,89673-67-6,89707-99-3,102045-32-9,135910-17-7)

Guidance literature:

With Dowex-50w (H⁺); at 0 ℃; for 24h; Inert atmosphere;

DOI:10.1016/j.bmc.2010.07.005

Reference yield: 98.0%

methanol (67-56-1) + D-xylofuranose (532-20-7,613-83-2,7261-25-8,7687-39-0,13221-22-2,14795-83-6,15761-67-8,20074-49-1,25545-03-3,25545-04-4,32445-75-3,34436-17-4,36441-93-7,36468-53-8,37110-85-3,37388-49-1,38029-69-5,40461-77-6,40461-89-0,41546-19-4,41546-20-7,41546-21-8,41546-26-3,41546-29-6,41546-30-9,41546-31-0,126872-16-0,131064-98-7) → methyl xylofuranoside (1824-96-0,1824-97-1,3795-68-4,3795-69-5,4229-54-3,5531-18-0,7473-45-2,13039-63-9,13039-64-0,13039-65-1,13039-67-3,22416-73-5,22861-09-2,25129-51-5,52485-92-4,52689-55-1,52689-56-2,56607-40-0,72880-70-7,79083-42-4,86782-30-1,86782-31-2,89615-03-2,89673-67-6,89707-99-3,102045-32-9,135910-17-7)

Guidance literature:

With acetyl chloride; In methanol; at 40 ℃; for 2.5h;

upstream raw materials:

methanol

D-Arabinose

D-arabinose diethyl dithioacetal

D-arabinofuranose

Downstream raw materials:

methyl 2,3,5-tri-O-benzyl-α-D-arabinofuranoside

methyl tri-O-benzoyl-α-D-arabinofuranoside

methyl 5-O-benzoyl-α-D-arabinofuranoside

methyl-β-D-arabinopyranoside