trichlorotitanium

Base Information

• Chemical Name: trichlorotitanium
• CAS No.: 2747-38-8
• Molecular Formula: CH3 Cl3 Ti
• Molecular Weight: 169.274
• Hs Code.: 2931900090
• Mol file: 2747-38-8.mol

Synonyms:Methyltitanium(IV)trichloride (6CI); Titanium, trichloromethyl- (7CI,8CI); Methyltitaniumchloride; Methyltitanium trichloride; Methyltrichlorotitanium;Trichloromethyltitanium

Chemical Property of trichlorotitanium

Chemical Property:

• Boiling Point: °Cat760mmHg
• Flash Point: °C
• PSA: 0.00000
• Density: g/cm³
• LogP: -8.53770

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of trichlorotitanium

There total 7 articles about trichlorotitanium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 50.0%

dimethyl zinc(II) (544-97-8) + titanium tetrachloride (7550-45-0) → methyltrichlorotitanium (2747-38-8)

Guidance literature:

In further solvent(s); byproducts: ZnCl2; solvent = 2-methylbutane; (Ar); ZnMe2 (0.029 mol) cooled to -196 °C; evacuation; 2-methylbutane distd. (vac.) into react. vessel followed by TiCl4 (0.056 mol); warming gradually to room temp.; mixt. stirred rapidly (1 h, room temp.); ZnCl2 filtered off; filtrate cooled to -78 °C; after 1-2 h, resulting ppt. isolated by decantation; this ppt. recrystd. twice (2-methylbutane) and dried (vac., -78 °C, several h); storage at -78 °C (Ar);

Reference yield:

tetramethylstannane (594-27-4) + titanium tetrachloride (7550-45-0) → trimethyltin(IV)chloride (1066-45-1) + methyltrichlorotitanium (2747-38-8)

Guidance literature:

Reference yield:

methyllithium (917-54-4) → methyltrichlorotitanium (2747-38-8)

Guidance literature:

With titanium tetrachloride; In diethyl ether; at -78 - -50 ℃; for 1.16667h;

upstream raw materials:

tetramethylstannane

titanium tetrachloride

trimethylaluminum

dimethyl zinc(II)

Downstream raw materials:

methyl-3 phenyl-3 pentane

2-methylhexan-2-ol

rac-octan-2-ol

2-Methyl-2-heptanol

Refernces

• 1、 Briant, Peter,Green, Jennifer,Haaland, Arne,Mollendal, Harald,Rypdal, Kristin,Tremmel, Janos. "". . p. 3434 - 3436. Retrieved 1989.
• 2、 Weiberth, Franz J.,Gill, Harpal S.,Lee, George E.,Ngo, Duc P.,Shrimp, Frederick L.,Chen, Xuemin,D'Netto, Geoffrey,Jackson, Bryan R.,Jiang, Ying,Kumar, Narendra,Roberts, Frederick,Zlotnikov, Evgeny. "Development of a Synthesis of a 2,3-Disubstituted 4,7-Diazaindole Including Large-Scale Application of CH3Li/TiCl4-Mediated Methylation of an Enolizable Ketone". . p. 806 - 811. Retrieved 2015/07/27.
• 3、 Dawoodi, Zain,Green, Malcolm L.H.,Mtetwa, Victor S. B.,Prout, Keith,Schultz, Arthur J.,et al.. "Evidence for Carbon-Hydrogen-Titanium Interactions: Synthesis and Crystal Stuctures of the Agostic Alkyls (R=Et or Me)". . p. 1629 - 1638. Retrieved 2007/10/02.