1,10-Diphenyldecane-1,10-dione

Base Information

• Chemical Name: 1,10-Diphenyldecane-1,10-dione
• CAS No.: 6268-61-7
• Molecular Formula: C22H26 O2
• Molecular Weight: 322.447
• Hs Code.: 2914399090
• NSC Number: 36278
• DSSTox Substance ID: DTXSID70284234
• Nikkaji Number: J1.370.239J
• Wikidata: Q82019099
• Mol file: 6268-61-7.mol

Synonyms:1,8-Dibenzoyloctane;1,10-diphenyldecane-1,10-dione;6268-61-7;1,10-Diphenyl-1,10-decanedione;NSC36278;Maybridge1_002442;DivK1c_001194;SCHEMBL8519287;HMS548G22;DTXSID70284234;BTBG 00037;NSC-36278;AKOS015839070;CDS1_000154;3-(BOC-AMINO)-4-HYDROXYBENZOICACID

Chemical Property of 1,10-Diphenyldecane-1,10-dione

Chemical Property:

• Vapor Pressure: 2.23E-09mmHg at 25°C
• Boiling Point: 480.1°Cat760mmHg
• Flash Point: 178.1°C
• PSA: 34.14000
• Density: 1.032g/cm³
• LogP: 5.87300
• XLogP3: 5.7
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 11
• Exact Mass: 322.193280068
• Heavy Atom Count: 24
• Complexity: 326

Purity/Quality:

98%min ^*data from raw suppliers

1,8-Dibenzoyloctane 97% ^*data from reagent suppliers

Safty Information:

• Hazard Codes: Xi

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C(C=C1)C(=O)CCCCCCCCC(=O)C2=CC=CC=C2

Technology Process of 1,10-Diphenyldecane-1,10-dione

There total 17 articles about 1,10-Diphenyldecane-1,10-dione which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

1,6-hexanediol (629-11-8) + acetophenone (98-86-2) → dypnone (495-45-4) + 1,10-diphenyl-decane-1,10-dione (6268-61-7)

Guidance literature:

With potassium hydroxide; bis(1,5-cyclooctadiene)diiridium(I) dichloride; triphenylphosphine; at 100 ℃; for 15h; Inert atmosphere;

DOI:10.1246/bcsj.81.689

Reference yield: 80.0%

→ 1,10-diphenyl-decane-1,10-dione (6268-61-7)

Guidance literature:

Reference yield: 21.0%

trimethyl((1-phenylcyclopentyl)peroxy)silane → phenyl butyl ketone (1009-14-9) + 1,10-diphenyl-decane-1,10-dione (6268-61-7)

Guidance literature:

With nickel(II) tetrafluoroborate hexahydrate; 2-[4,5-dihydro-1,3-oxazol-2-yl]pyridine; zinc; In dimethyl sulfoxide; at 60 ℃; for 40h;

DOI:10.1021/acs.joc.1c02674

upstream raw materials:

sebacoyl chloride

benzene

1,8-Dibenzoyl-octatetraen-(1,3,5,7)

trans,cis,cis,trans-1,10-Diphenyl-deca-2,4,6,8-tetraen-1,10-dion

Downstream raw materials:

2,11-diphenyl-dodecane

1,2-Diphenylcyclododecen

2,11-dicyclohexyl-dodecane

1,10-diphenyl-decane-1,10-diol