10-methoxybicyclo[4.4.1]undeca-1,3,5,7,9-pentaene

Base Information

• Chemical Name: 10-methoxybicyclo[4.4.1]undeca-1,3,5,7,9-pentaene
• CAS No.: 58853-55-7
• Molecular Formula: C12H12 O
• Molecular Weight: 172.22
• Mol file: 58853-55-7.mol

Synonyms:2-Methoxy-1,6-methano[10]annulene;2-Methoxybicyclo[4.4.1]undeca-1,3,5,7,9-pentaene

Chemical Property of 10-methoxybicyclo[4.4.1]undeca-1,3,5,7,9-pentaene

Chemical Property:

• Vapor Pressure: 1.71E-05mmHg at 25°C
• Boiling Point: 375.2°C at 760 mmHg
• Flash Point: 178.4°C
• Density: 1.06g/cm³

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 10-methoxybicyclo[4.4.1]undeca-1,3,5,7,9-pentaene

There total 4 articles about 10-methoxybicyclo[4.4.1]undeca-1,3,5,7,9-pentaene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

methanol (67-56-1) + 2-bromo-1,6-methano[10]annulene (15825-92-0,107134-29-2,107134-35-0) → 2-Methoxy-1,6-methano-<10>annulene (58853-55-7)

Guidance literature:

In N,N,N,N,N,N-hexamethylphosphoric triamide; at 80 ℃; for 2h;

DOI:10.1021/ja00349a001

Reference yield:

1,6-methano[10]annulene (2443-46-1) → 2-Methoxy-1,6-methano-<10>annulene (58853-55-7)

Guidance literature:

Multi-step reaction with 2 steps

1: NBS

2: CuI

With N-Bromosuccinimide; copper(l) iodide;

Reference yield:

2-bromo-1,6-methano[10]annulene (15825-92-0,107134-29-2,107134-35-0) + sodium methylate (124-41-4) → 2-Methoxy-1,6-methano-<10>annulene (58853-55-7)

Guidance literature:

With copper(l) iodide;

upstream raw materials:

2-bromo-1,6-methano[10]annulene

sodium methylate

methanol

1,6-methano[10]annulene

Downstream raw materials:

5-[(4-Chloro-2-nitro-phenyl)-hydrazono]-bicyclo[4.4.1]undeca-1⁽¹⁰⁾,3,6,8-tetraen-2-one

5-[(4-Methoxy-2-nitro-phenyl)-hydrazono]-bicyclo[4.4.1]undeca-1⁽¹⁰⁾,3,6,8-tetraen-2-one

Bicyclo<4.4.1>undeca-3,6,8,10-tetraen-2,5-dion-2-(2-methyl-6-nitrophenylhydrazon)

Bicyclo<4.4.1>undeca-3,6,8,10-tetraen-2,5-dion-2-(4-nitrophenyl)hydrazon

Post a RFQ

Cas No.:

Product Name:

Quantity:

Please select Metric Ton KG G Pound L ML

Email:

Company name:

Valid Period:

Detailed Requirements:

• Sample
• MOQ
• GMP
• FDA
• Price
  FOB CIF CFR EXW
• Urgent purchase

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

Remove

Submit

1

What can I do for you?
Get Best Price

Get Best Price for 58853-55-7 10-methoxybicyclo[4.4.1]undeca-1,3,5,7,9-pentaene

Send

Send

Metric Ton KG G Pound L ML

Send

Send