1-Chloro-1,1,2,2,3,3,3-heptafluoropropane

Base Information

• Chemical Name: 1-Chloro-1,1,2,2,3,3,3-heptafluoropropane
• CAS No.: 422-86-6
• Molecular Formula: C3Cl F7
• Molecular Weight: 204.475
• Hs Code.: 2903772026
• European Community (EC) Number: 207-024-2
• DSSTox Substance ID: DTXSID8059972
• Nikkaji Number: J196.095D
• Wikidata: Q81989018
• Mol file: 422-86-6.mol

Synonyms:422-86-6;1-Chloro-1,1,2,2,3,3,3-heptafluoropropane;1-Chloroheptafluoropropane;CFC-217ca;Heptafluoropropyl chloride;Cfc 217;Chloroheptafluoropropane;1-Chloroheptafluoropropane (FC 217A);1-chloro-heptafluoro-propane;CFC-217;EINECS 207-024-2;PROPANE, 1-CHLORO-1,1,2,2,3,3,3-HEPTAFLUORO-;Propane, chloroheptafluoro-;SCHEMBL180330;DTXSID8059972;MFCD00040134;AKOS016015381;1-chloro-1,1,2,2,3,3,3-heptafluoro-propane;A825836;30143-46-5

Chemical Property of 1-Chloro-1,1,2,2,3,3,3-heptafluoropropane

Chemical Property:

• Vapor Pressure: 1840mmHg at 25°C
• Refractive Index: 1.1920 (estimate)
• Boiling Point: °Cat760mmHg
• Flash Point: °C
• PSA: 0.00000
• Density: 1.6g/cm³
• LogP: 3.01560
• XLogP3: 3.4
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 7
• Rotatable Bond Count: 1
• Exact Mass: 203.9576748
• Heavy Atom Count: 11
• Complexity: 146

Purity/Quality:

99% ^*data from raw suppliers

1-Chloroheptafluoropropane ^*data from reagent suppliers

Safty Information:

• Hazard Codes: Xi

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C(C(F)(F)F)(C(F)(F)Cl)(F)F

Technology Process of 1-Chloro-1,1,2,2,3,3,3-heptafluoropropane

There total 25 articles about 1-Chloro-1,1,2,2,3,3,3-heptafluoropropane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 63.0%

1-Chloropropane (540-54-5) → perfluoropropyl chloride (422-86-6)

Guidance literature:

With fluorine; at -30 - 0 ℃; Mechanism; Product distribution; Irradiation; steady-state flow process; the hydrocarbon vapor is condensed onto a NaF preaerosol and then subjected to attack by an excess of elemental F in He at first in the dark, then under UV irradiation;

DOI:10.1021/jo00189a014

Reference yield: 33.0%

isopropyl chloride (75-29-6) → perfluoropropyl chloride (422-86-6) + 2-Chloro-F-propane (76-18-6)

Guidance literature:

With fluorine; at -30 - 0 ℃; Mechanism; Product distribution; Irradiation; steady-state flow process; the hydrocarbon vapor is condensed onto a NaF preaerosol and then subjected to attack by an excess of elemental F in He at first in the dark, then under UV irradiation;

DOI:10.1021/jo00189a014

Reference yield:

1,1,1-trichloro-2,2,3,3,3-pentafluoropropane (4259-43-2) → 3-chloro-1,1,1,2,2-pentafluoropropane (422-02-6) + 2,2,3-trichloro-1,1,1,3,3-pentafluoropropane (1599-41-3) + 1,1,1-trifluoropropane (421-07-8) + 3,3-dichloro-1,1,1,2,2-pentafluoropropane (422-56-0) + perfluoropropyl chloride (422-86-6) + 1,1,1,2-tetrafluoropropane (421-48-7) + 1-chloro-1,1,2,2,3-pentafluoropropane (677-55-4) + 1,1,1,2,2-pentafluoropropane (1814-88-6)

Guidance literature:

With hydrogen; fluorided platinum on aluminum oxide; at 250 ℃; Product distribution / selectivity;

upstream raw materials:

HFC-227ca

1,3-dichlorohexafluoropropane

1-chloro-1,2,2,3,3,3-hexafluoro-1-iodo-propane

1-chloro-1,1,2,2,3,3-hexafluoropropane

Downstream raw materials:

freon-218

Refernces

• 1、 -. "Addition of trifluoromethanes to fluoroolefins and isomerization of monohaloperfluoro alkanes". . . Retrieved 2008/06/13.
• 2、 Zakharov, V. Yu.,Denisov, A. K.,Novikova, M. D.. "DIRECT GAS-PHASE CATALYTIC FLUORINATION OF PARTIALLY FLUORINATED ORGANIC COMPOUNDS". . p. 1942 - 1945. Retrieved 2007/10/03.