eta5-Methylcyclopentadienyl titanium trichloride

Base Information

• Chemical Name: eta5-Methylcyclopentadienyl titanium trichloride
• CAS No.: 1282-31-1
• Molecular Formula: C6H7 Cl3 Ti
• Molecular Weight: 233.361
• Mol file: 1282-31-1.mol

Synonyms:eta5-Methylcyclopentadienyl titanium trichloride;1282-31-1;5-methylcyclopenta-1,3-diene;trichlorotitanium;.eta.5-Methylcyclopentadienyl titanium trichloride

Chemical Property of eta5-Methylcyclopentadienyl titanium trichloride

Chemical Property:

• Vapor Pressure: 94.8mmHg at 25°C
• Boiling Point: 80.4°Cat760mmHg
• Flash Point: °C
• PSA: 0.00000
• Density: g/cm³
• LogP: 2.98340
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 0
• Exact Mass: 231.909274
• Heavy Atom Count: 10
• Complexity: 116

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C[C-]1C=CC=C1.Cl[Ti](Cl)Cl

Technology Process of eta5-Methylcyclopentadienyl titanium trichloride

There total 3 articles about eta5-Methylcyclopentadienyl titanium trichloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

titanium tetrachloride (7550-45-0) → chloro-trimethyl-silane (75-77-4) + (η-5-methylcyclopentadienyl)titanium trichloride (1282-31-1)

Guidance literature:

With CH₃C₅H₄Si(CH₃)3;

Reference yield: 80.0%

chloro-trimethyl-silane (75-77-4) + titanium tetrachloride (7550-45-0) → (η-5-methylcyclopentadienyl)titanium trichloride (1282-31-1)

Guidance literature:

With methylcyclopentadienyl lithium; In not given; synthesis according to Cardoso's method (Cardoso, A.M. Clark, R.J.H. Moorhouse S.; J. Chem. Soc. Dalton Trans. 1980 p.1156); condensation of H3CCpLi with ClSiMe3 gives mixt. of isomers of H3CCpSi(CH3)3; condensation with TiCl4;;

Reference yield: 56.0%

dichlorobis(η5-methylcyclopentadienyl)titanium(IV) (1282-40-2) + titanium tetrachloride (7550-45-0) → (η-5-methylcyclopentadienyl)titanium trichloride (1282-31-1)

Guidance literature:

In xylene; refluxed overnight; the solvent and excess reagents removed in vac., the product sublimed;

upstream raw materials:

chloro-trimethyl-silane

titanium tetrachloride

dichlorobis(η5-methylcyclopentadienyl)titanium(IV)

Downstream raw materials:

chloro-trimethyl-silane

(CH₃C₅H₄)4Ti₄S₄

Refernces

• 1、 Paquette, Leo A.,Moriarty, Kevin J.,Meunier, Philippe,Gautheron, Bernard,Crocq, Véronique. "Stereocontrolled bifacial complexation of the isodicyclopentadienyl ligand to cyclopentadienyltitanium dichloride fragments". . p. 1873 - 1875. Retrieved 2008/10/08.
• 2、 Petersen, Jeffrey L.. "Polynuclear oxo-bridged cyclopentadienyl transition-metal complexes. Formation and structural characterization of the titanoxane tetramer, [(η5-C5H4CH3)TiCl(μ-O)] 4". . p. 181 - 185. Retrieved 2008/10/08.