Methyl 2,5-dihydro-2,5-dimethoxy-2-furancarboxylate

Base Information

Chemical Name:Methyl 2,5-dihydro-2,5-dimethoxy-2-furancarboxylate
CAS No.:62435-72-7
Molecular Formula:C8H12O5
Molecular Weight:188.18
Hs Code.:29321900
European Community (EC) Number:263-540-8
DSSTox Substance ID:DTXSID50978003
Nikkaji Number:J307.043C
Mol file:62435-72-7.mol

Synonyms:62435-72-7;Methyl 2,5-dihydro-2,5-dimethoxy-2-furancarboxylate;methyl 2,5-dimethoxy-2,5-dihydrofuran-2-carboxylate;methyl 2,5-dimethoxy-2H-furan-5-carboxylate;EINECS 263-540-8;Methyl 2,5-dihydro-2,5-dimethoxyfuran-2-carboxylate;SCHEMBL6889870;DTXSID50978003;AKOS015914163;FT-0628414;EN300-7536375;A833769;J-640059;2,5-Dihydro-2,5-dimethoxy-2-furancarboxylic acid methyl ester;2-Furancarboxylic acid,2,5-dihydro-2,5-dimethoxy-,methyl ester

Suppliers and Price of Methyl 2,5-dihydro-2,5-dimethoxy-2-furancarboxylate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Sigma-Aldrich
Methyl 2,5-dihydro-2,5-dimethoxy-2-furancarboxylate, mixture of cis and trans technical grade, 85%
5g
$ 173.00

American Custom Chemicals Corporation
METHYL 2,5-DIHYDRO-2,5-DIMETHOXY-2-FURANCARBOXYLATE 95.00%
5G
$ 1027.80

AHH
Methyl2,5-dihydro-2,5-dimethoxy-2-furancarboxylate 85%
25g
$ 520.00

Total 11 raw suppliers

Chemical Property of Methyl 2,5-dihydro-2,5-dimethoxy-2-furancarboxylate

Chemical Property:

Appearance/Colour:colorless to light yellow liquid
Vapor Pressure:0.0288mmHg at 25°C
Refractive Index:n20/D 1.449(lit.)
Boiling Point:245.4 °C at 760 mmHg
Flash Point:104.4 °C
PSA：53.99000
Density:1.18 g/cm³
LogP:0.06100
XLogP3:0.2
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:5
Rotatable Bond Count:4
Exact Mass:188.06847348
Heavy Atom Count:13
Complexity:225

Purity/Quality:

97% ^*data from raw suppliers

Methyl 2,5-dihydro-2,5-dimethoxy-2-furancarboxylate, mixture of cis and trans technical grade, 85% ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:
Safety Statements: 24/25

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:COC1C=CC(O1)(C(=O)OC)OC

Technology Process of Methyl 2,5-dihydro-2,5-dimethoxy-2-furancarboxylate

There total 8 articles about Methyl 2,5-dihydro-2,5-dimethoxy-2-furancarboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

: 67-56-1
methanol

: 614-99-3
Ethyl 2-furoate

: 62435-72-7
2,5-dimethoxy-2,5-dihydro-furan-2-carboxylic acid methyl ester

Guidance literature:: Ethyl 2-furoate; With sulfuric acid; at -15 ℃; Electrochemical reaction;

methanol; With sodium methylate;
DOI:10.1021/ol061681r

Reference yield:

: 67-56-1
methanol

: 611-13-2
2-furoic acid methyl ester

: 62435-72-7
2,5-dimethoxy-2,5-dihydro-furan-2-carboxylic acid methyl ester

Guidance literature:: With sulfuric acid; Electrolysis;

Reference yield:

: 614-99-3
Ethyl 2-furoate

: 62435-72-7
2,5-dimethoxy-2,5-dihydro-furan-2-carboxylic acid methyl ester

Guidance literature:: Multi-step reaction with 2 steps

1: conc. H₂SO₄ / -15 °C / Electrochemical reaction; Pt-anode; Ni-cathode

2: 14.5 g / MeONa

With sulfuric acid; sodium methylate;
DOI:10.1021/ol026460+