1H-Benz[de]isoquinoline-1,3(2H)-dione, 6-bromo-2-methyl-

Base Information

Chemical Name:1H-Benz[de]isoquinoline-1,3(2H)-dione, 6-bromo-2-methyl-
CAS No.:4116-90-9
Deprecated CAS:1445745-63-0
Molecular Formula:C13H8 Br N O2
Molecular Weight:290.116
Hs Code.:2933990090
European Community (EC) Number:223-908-0
DSSTox Substance ID:DTXSID0063311
Nikkaji Number:J33.559B
Wikidata:Q81990650
ChEMBL ID:CHEMBL1886820
Mol file:4116-90-9.mol

Synonyms:4116-90-9;4-Bromo-N-methyl-1,8-naphthalimide;6-bromo-2-methyl-1h-benz[de]isoquinoline-1,3(2h)-dione;1H-Benz[de]isoquinoline-1,3(2H)-dione, 6-bromo-2-methyl-;6-bromo-2-methylbenzo[de]isoquinoline-1,3-dione;C13H8BrNO2;4-Bromonaphthalic methylimide;6-bromo-2-methyl-1H-benzo[de]isoquinoline-1,3(2H)-dione;EINECS 223-908-0;1H-Benz(de)isoquinoline-1,3(2H)-dione, 6-bromo-2-methyl-;6-Bromo-2-methyl-1H-benz(de)isoquinoline-1,3(2H)-dione;MLS001076002;SCHEMBL4866412;CHEMBL1886820;DTXSID0063311;HMS2799O06;Naphthalimide, 4-bromo-N-methyl-;MFCD00446021;STK753305;AKOS000439893;BS-28471;SMR000473085;CS-0206696;4-Bromo-N-methyl-1,8-naphthalenedicarboximide;E83387;SR-01000513098;SR-01000513098-1;W-109949;8-bromo-3-methyl-3-azatricyclo[7.3.1.0?,??]trideca-1(13),5,7,9,11-pentaene-2,4-dione;8-BRomo-3-methyl-3-azatricyclo[7.3.1.0^{5,13}]trideca-1(12),5,7,9(13),10-pentaene-2,4-dione

Suppliers and Price of 1H-Benz[de]isoquinoline-1,3(2H)-dione, 6-bromo-2-methyl-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 7 raw suppliers

Chemical Property of 1H-Benz[de]isoquinoline-1,3(2H)-dione, 6-bromo-2-methyl-

Chemical Property:

Vapor Pressure:6.89E-08mmHg at 25°C
Boiling Point:438.5°Cat760mmHg
Flash Point:219°C
PSA：39.07000
Density:1.678g/cm³
LogP:2.25220
XLogP3:2.8
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:0
Exact Mass:288.97384
Heavy Atom Count:17
Complexity:370

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CN1C(=O)C2=C3C(=C(C=C2)Br)C=CC=C3C1=O

Technology Process of 1H-Benz[de]isoquinoline-1,3(2H)-dione, 6-bromo-2-methyl-

There total 6 articles about 1H-Benz[de]isoquinoline-1,3(2H)-dione, 6-bromo-2-methyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

: 81-86-7
4-bromo-1,8-naphthalenedicarboxylic anhydride

: 74-89-5
methylamine

: 4116-90-9
4-bromo-N-methyl-1,8-naphthalimide

Guidance literature:: With acetic acid; at 100 ℃; for 2h; Inert atmosphere;

Reference yield: 88.0%

: 52559-36-1
4-bromonaphthalene-1,8-dicarboximide

: 74-88-4
methyl iodide

: 4116-90-9
4-bromo-N-methyl-1,8-naphthalimide

Guidance literature:: With potassium carbonate; In N,N-dimethyl-formamide; at 50 ℃; for 24h;

Reference yield:

: 81-84-5
1,8-Naphthalic anhydride

: 4116-90-9
4-bromo-N-methyl-1,8-naphthalimide

Guidance literature:: Multi-step reaction with 2 steps

1: bromine; potassium hydroxide / water / 2.67 h / 20 - 60 °C

2: ethanol / 4 h / Reflux

With bromine; potassium hydroxide; In ethanol; water;
DOI:10.1039/c1nj20058e