Aurate(1-),tetrabromo-, (SP-4-1)- (9CI)

Base Information

• Chemical Name: Aurate(1-),tetrabromo-, (SP-4-1)- (9CI)
• CAS No.: 14337-14-5
• Molecular Formula: AuBr4
• Molecular Weight: 516.582
• Mol file: 14337-14-5.mol

Synonyms:Aurate(1-),tetrabromo- (8CI); Bromoaurate(III); Tetrabromoaurate(1-);Tetrabromoaurate(III)

Chemical Property of Aurate(1-),tetrabromo-, (SP-4-1)- (9CI)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Aurate(1-),tetrabromo-, (SP-4-1)- (9CI)

There total 2 articles about Aurate(1-),tetrabromo-, (SP-4-1)- (9CI) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

AuBr3(SCN)(1-) + sodium bromide (7647-15-6) → tetrabromo aurate (III) (1-) (14337-14-5) + sodium thiocyanide (540-72-7)

Guidance literature:

Reference yield:

tetra-n-butylammonium dibromoaurate(I) + dichloromethane (75-09-2) → tetrachloroaurate(III)(1-) (14337-12-3) + tetrabromo aurate (III) (1-) (14337-14-5)

Guidance literature:

In acetonitrile; Irradiation (UV/VIS); photolysis in deaerated CH3CN containing CH2Cl2; detected by UV-visible spectrophotometry;

Reference yield:

tetrabromo aurate (III) (1-) (14337-14-5) + uracil (66-22-8,144104-68-7,18324-22-6,27072-01-1,2920-92-5,51953-19-6) → 5-bromouracil (51-20-7) + dibromidoaurate(I)

Guidance literature:

In dimethylsulfoxide-d6; water; byproducts: 5-bromo-6-hydroxy-5,6-dihydrouracil; reduction reaction at 25°C; monitored by NMR-spectroscopy; Kinetics;

DOI:10.1016/S0020-1693(00)80946-9

upstream raw materials:

dichloromethane

sodium bromide

Downstream raw materials:

5-bromouracil

bromide

5-bromouridine