borane ethylenediaMine coMplex

Base Information

• Chemical Name: borane ethylenediaMine coMplex
• CAS No.: 15165-88-5
• Molecular Formula: C2H14 B2 N2
• Molecular Weight: 87.7686
• Mol file: 15165-88-5.mol

Synonyms:Boron,[m-(1,2-ethanediamine-N:N')]hexahydrodi-;Ethylenediamine, compd. with BH3 (1:2) (6CI,7CI); Ethylenediamine, compd. withborane (1:2) (8CI); Borane, compd. with 1,2-ethanediamine (2:1); Borane, compd.with ethylenediamine (2:1) (8CI); 1,2-Ethanediamine, compd. with borane (1:2);Ethylenediaminebisborane; NSC 114043

Chemical Property of borane ethylenediaMine coMplex

Chemical Property:

• Melting Point: 114-130°C (dec.)
• PSA: 52.04000
• LogP: -2.06340

Purity/Quality:

98%,99%, ^*data from raw suppliers

Borane ethylenediamine complex 96% ^*data from reagent suppliers

Safty Information:

• Hazard Codes: F,Xi
• Statements: 11-36/37/38
• Safety Statements: 16-26

MSDS Files:

SDS file from LookChem

Useful:

• Uses: Enantioselective hydride attack of borane-ethylenediamine complex on inclusion compounds of ketones and certain diols and β-cyclodextrin may form optically active alcohols.

Technology Process of borane ethylenediaMine coMplex

There total 9 articles about borane ethylenediaMine coMplex which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

dimethylsulfide borane complex (13292-87-0) + ethylenediamine (107-15-3,85404-18-8) → 1,2-diaminoethane-bis-borane (15165-88-5)

Guidance literature:

at 0 ℃; for 5h; Temperature; Time; Cooling with ice;

Reference yield: 85.0%

ethylenediamine (107-15-3,85404-18-8) + diborane (19287-45-7) → 1,2-diaminoethane-bis-borane (15165-88-5)

Guidance literature:

at 0 ℃; for 5h;

Reference yield: 83.0%

sodium tetrahydroborate (16940-66-2) + ethylenediamine (107-15-3,85404-18-8) → 1,2-diaminoethane-bis-borane (15165-88-5)

Guidance literature:

With ammonium sulfate; In tetrahydrofuran; for 8h; Reflux;

DOI:10.1021/acs.inorgchem.5b00572

upstream raw materials:

ethylenediamine

diborane

borane-THF

sodium tetrahydroborate

Downstream raw materials:

(H₂NC₂H₄)H₂N*BH₃

trimethylamine-borane

1,2-diaminoethane dihydrochloride

1,2-ethanediammonium