Benzyl tert-butyl nitroxide

Base Information

• Chemical Name: Benzyl tert-butyl nitroxide
• CAS No.: 24293-08-1
• Molecular Formula: C11H16 N O
• Molecular Weight: 178.254
• DSSTox Substance ID: DTXSID60947129
• Nikkaji Number: J1.135.719I
• Mol file: 24293-08-1.mol

Synonyms:24293-08-1;Benzyl tert-butyl nitroxide;Nitroxide, benzyl tert-butyl;C-Phenyl-N-(t-butyl)nitrone;DTXSID60947129;[Benzyl(tert-butyl)amino]oxidanyl;Nitroxide, 1,1-dimethylethyl phenylmethyl

Chemical Property of Benzyl tert-butyl nitroxide

Chemical Property:

• Boiling Point: °Cat760mmHg
• Flash Point: °C
• PSA: 3.24000
• Density: g/cm³
• LogP: 2.63260
• XLogP3: 2.3
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 3
• Exact Mass: 178.123189134
• Heavy Atom Count: 13
• Complexity: 145

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC(C)(C)N(CC1=CC=CC=C1)[O]

Technology Process of Benzyl tert-butyl nitroxide

There total 13 articles about Benzyl tert-butyl nitroxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

t-butylnitrite (917-95-3) → di-tert-butyl nitroxide (2406-25-9,44871-19-4) + t-butyl-t-butoxy nitroxide (52323-95-2) + N-tert-butyl-N-benzylnitroxyl (24293-08-1) + Benzyloxy-tert.butyl-aminyloxid (109492-49-1)

Guidance literature:

With 18-crown-6 ether; potassium ozonate; In toluene; at -50 - 0 ℃; Product distribution; with potassium superoxide, too;

DOI:10.1039/f19878300211

Reference yield:

N2, N2-dibenzylmethanesulfonohydrazide (86768-73-2) → di-tert-butyl nitroxide (2406-25-9,44871-19-4) + N-tert-butyl-N-benzylnitroxyl (24293-08-1)

Guidance literature:

With t-butylnitrite; In diethylene glycol dimethyl ether; Product distribution; Mechanism;

Reference yield:

N-tert-butyl-α-phenylnitrone (3376-24-7,68315-30-0) → N-tert-butyl-N-benzylnitroxyl (24293-08-1)

Guidance literature:

With hydrogen; palladium; In dichloromethane; at 25 ℃; for 0.166667h;

DOI:10.1039/ft9949003341

upstream raw materials:

dibenzyl disulphide

t-butylnitrite

(Z)-N-benzylidene-2-methylpropan-2-amine oxide

N-benzyl-N-(tert-butyl)hydroxylamine

Refernces

• 1、 Mileo, Elisabetta,Franchi, Paola,Gotti, Roberto,Bendazzoli, Claudia,Mezzina, Elisabetta,Lucarini, Marco. "An EPR method for measuring the rate of distribution of organic substrates between cyclodextrin, micelles and water". . p. 1311 - 1313. Retrieved 2008.
• 2、 Conte, Marco,Miyamura, Hiroyuki,Kobayashi, Shu,Chechik, Victor. "Spin trapping of Au-H intermediate in the alcohol oxidation by supportedand unsupported gold catalysts". supporting information; experimental part. p. 7189 - 7196. Retrieved 2009/09/30.