1,3-Dioxolane, 2-methyl-2,4-diphenyl-

Base Information

• Chemical Name: 1,3-Dioxolane, 2-methyl-2,4-diphenyl-
• CAS No.: 101854-08-4
• Molecular Formula: C16H16O2
• Molecular Weight: 240.302
• NSC Number: 50946
• DSSTox Substance ID: DTXSID80287413
• Mol file: 101854-08-4.mol

Synonyms:1,3-Dioxolane, 2-methyl-2,4-diphenyl-;101854-08-4;NSC50946;DTXSID80287413;NSC-50946

Chemical Property of 1,3-Dioxolane, 2-methyl-2,4-diphenyl-

Chemical Property:

• XLogP3: 3
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 2
• Exact Mass: 240.115029749
• Heavy Atom Count: 18
• Complexity: 266

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC1(OCC(O1)C2=CC=CC=C2)C3=CC=CC=C3

Technology Process of 1,3-Dioxolane, 2-methyl-2,4-diphenyl-

There total 4 articles about 1,3-Dioxolane, 2-methyl-2,4-diphenyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

styrene oxide (96-09-3) + acetophenone (98-86-2) → 2-methyl-2,4-diphenyl-[1,3]dioxolane (101854-08-4)

Guidance literature:

With FeOx-pillared bentonite; In dichloromethane; for 2h; Reflux;

DOI:10.1016/j.catcom.2014.05.002

Reference yield: 30.0%

phenylethane 1,2-diol (93-56-1) + acetophenone (98-86-2) → 2-methyl-2,4-diphenyl-[1,3]dioxolane (101854-08-4)

Guidance literature:

With iron(III) chloride hexahydrate; In tetrahydrofuran; at 20 ℃; for 2h;

DOI:10.1016/j.crci.2010.12.001

Reference yield:

styrene oxide (96-09-3) → 2-benzyl-4-phenyl-[1,3]dioxolane (4362-20-3) + 2-methyl-2,4-diphenyl-[1,3]dioxolane (101854-08-4)

Guidance literature:

With hydrogenchloride;

DOI:10.1021/ja01624a043

upstream raw materials:

styrene oxide

hydrogenchloride

phenylethane 1,2-diol

acetophenone

Downstream raw materials:

acetophenone