Vanadium, tetracarbonylbis(triphenylphosphine)-

Base Information

• Chemical Name: Vanadium, tetracarbonylbis(triphenylphosphine)-
• CAS No.: 10210-62-5
• Molecular Formula: C₄₀H₃₀O₄P₂V
• Molecular Weight: 687.565
• Mol file: 10210-62-5.mol

Synonyms:

Chemical Property of Vanadium, tetracarbonylbis(triphenylphosphine)-

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Vanadium, tetracarbonylbis(triphenylphosphine)-

There total 2 articles about Vanadium, tetracarbonylbis(triphenylphosphine)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

V(CO)5{P(C6H5)3} (72622-82-3) + triphenylphosphine (603-35-0) → V(CO)4(P(C6H5)3)2 (10210-62-5)

Guidance literature:

In hexane; at 25°C;; Kinetics;

DOI:10.1021/ja00313a016

Reference yield:

vanadium hexacarbonyl (14024-00-1) → tetracarbonyl bis-(triphenyl phosphine) vanadium (10210-62-5) + V(CO)5{P(C6H5)3} (72622-82-3)

Guidance literature:

With PPh₃; In hexane; under N2; solvent removed in vac. at room temp.;

Reference yield:

tetracarbonyl bis-(triphenyl phosphine) vanadium (10210-62-5) + tetraethylammonium iodide (68-05-3) → tetraethyl ammonium pentacarbonyl (triphenyl phosphine) vanadat (10170-61-3)

Guidance literature:

With sodium amalgam; In ethanol; shaking a suspension of 3 g (4.36 mmol) V(CO)4(C18H15P)2 in 80 ml ethanol with an excess of Na amalgam (1 % Na) (15-30 minutes) and addition of an excess of a solution of the iodide in water;; precipitation; washing with H2O, ethanol and ether, recrystallization from acetone/ether;;

upstream raw materials:

vanadium hexacarbonyl

V(CO)5{P(C₆H₅)3}

triphenylphosphine

Downstream raw materials:

tetraethyl ammonium pentacarbonyl (triphenyl phosphine) vanadat

tetramethyl ammonium pentacarbonyl (triphenyl phosphine) vanadat

Refernces

• 1、 Ellis, John E.,Faltynek, Robert A.,Rochfort, Gary L.,Stevens, Robert E.,Zank, Gregg A.. "Synthesis and properties of (triphenylphosphine)pentacarbonylvanadiuin(0), V(CO)5Ph3P". . p. 1082 - 1085. Retrieved 2008/10/08.