Triethyl(2-phenylprop-2-en-1-yl)silane

Base Information

• Chemical Name: Triethyl(2-phenylprop-2-en-1-yl)silane
• CAS No.: 104014-97-3
• Molecular Formula: C15H24Si
• Molecular Weight: 232.441
• DSSTox Substance ID: DTXSID40595642
• Nikkaji Number: J2.001.910G
• Wikidata: Q82490705
• Mol file: 104014-97-3.mol

Synonyms:104014-97-3;Triethyl(2-phenylprop-2-en-1-yl)silane;DTXSID40595642

Chemical Property of Triethyl(2-phenylprop-2-en-1-yl)silane

Chemical Property:

• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 6
• Exact Mass: 232.164727300
• Heavy Atom Count: 16
• Complexity: 201

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC[Si](CC)(CC)CC(=C)C1=CC=CC=C1

Technology Process of Triethyl(2-phenylprop-2-en-1-yl)silane

There total 5 articles about Triethyl(2-phenylprop-2-en-1-yl)silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

triethylsilyl chloride (994-30-9) + (3-phenoxyprop-1-en-2-yl)benzene (36963-72-1) → 2-phenyl-3-(triethylsilyl)prop-1-ene (104014-97-3)

Guidance literature:

With bis(cyclopentadienyl)titanium dichloride; butyl magnesium bromide; In tetrahydrofuran; at -20 ℃; for 15h;

DOI:10.1016/j.tetlet.2003.12.101

Reference yield: 71.0%

triethylsilyl chloride (994-30-9) + (3-phenoxyprop-1-en-2-yl)benzene (36963-72-1) + butyl magnesium bromide (693-04-9) → (1-methylenehexyl)benzene (24066-86-2) + 2-phenyl-3-(triethylsilyl)prop-1-ene (104014-97-3) + isopropenylbenzene (98-83-9,6144-04-3,25014-31-7,42612-14-6)

Guidance literature:

nickel dichloride; In tetrahydrofuran; at 25 ℃; for 1h;

DOI:10.1002/adsc.200404192

Reference yield:

triethylsilane (617-86-7) + isopropenylbenzene (98-83-9,6144-04-3,25014-31-7,42612-14-6) → 2-phenyl-3-(triethylsilyl)prop-1-ene (104014-97-3) + (E)-1-methyl-1-phenyl-2-(triethylsilyl)ethylene (104015-00-1)

Guidance literature:

With di-tert-butyl peroxide; copper diacetate; In tert-butyl alcohol; at 110 ℃; for 24h; Overall yield = 65 %; stereoselective reaction; Inert atmosphere;

DOI:10.1039/c6cc05509e

upstream raw materials:

triethylsilane

isopropenylbenzene

triethylsilyl chloride

(3-phenoxyprop-1-en-2-yl)benzene

Refernces

• 1、 Nii, Shinsuke,Terao, Jun,Kambe, Nobuaki. "Titanocene-catalyzed formation of allylsilanes from allyl ethers and chlorosilanes". . p. 1699 - 1702. Retrieved 2007/10/03.
• 2、 -. "Tetracyclic triterpene derivatives with immunosuppressant activity". . . Retrieved 2008/06/13.