ethyl 3,3-diphenyloxirane-2-carboxylate

Base Information

• Chemical Name: ethyl 3,3-diphenyloxirane-2-carboxylate
• CAS No.: 5449-40-1
• Molecular Formula: C17H16 O3
• Molecular Weight: 268.312
• Hs Code.: 2918990090
• Mol file: 5449-40-1.mol

Synonyms:Glycidicacid, 3,3-diphenyl-, ethyl ester (6CI,7CI,8CI); Oxiranecarboxylic acid,3,3-diphenyl-, ethyl ester (9CI); Ethyl 3,3-diphenylglycidate; Ethyl3,3-diphenyloxiranecarboxylate; NSC 16323

Chemical Property of ethyl 3,3-diphenyloxirane-2-carboxylate

Chemical Property:

• Vapor Pressure: 1.43E-05mmHg at 25°C
• Boiling Point: 366.8°Cat760mmHg
• Flash Point: 153.4°C
• PSA: 38.83000
• Density: 1.191g/cm³
• LogP: 2.89210

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of ethyl 3,3-diphenyloxirane-2-carboxylate

There total 7 articles about ethyl 3,3-diphenyloxirane-2-carboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

2-Bromo-3-hydroxy-3,3-diphenyl-propionic acid ethyl ester (114091-83-7) → ethyl 2,3-epoxy-3,3-diphenylpropionate (5449-40-1)

Guidance literature:

With potassium carbonate;

Reference yield: 69.0%

benzophenone (119-61-9) + chloroacetic acid ethyl ester (105-39-5) → ethyl 2,3-epoxy-3,3-diphenylpropionate (5449-40-1)

Guidance literature:

With potassium tert-butylate; In tert-butyl alcohol; for 10h;

DOI:10.1002/1099-0690(200205)2002:9<1523::AID-EJOC1523>3.0.CO;2-S

Reference yield:

→ ethyl 2,3-epoxy-3,3-diphenylpropionate (5449-40-1)

Guidance literature:

With water;

DOI:10.1021/ja01641a013

upstream raw materials:

benzophenone

chloroacetic acid ethyl ester

diethyl ether

sodium benzophenone ketyl

Downstream raw materials:

ethyl 2-oxo-3,3-diphenylpropanoate

3-Fluoro-2-hydroxy-3,3-diphenyl-propionic acid ethyl ester

3-Ethoxy-2-hydroxy-3,3-diphenyl-propionic acid ethyl ester

2,3-epoxy-3,3-diphenyl-propionic acid amide