Stannane, benzoyltrimethyl-

Base Information

• Chemical Name: Stannane, benzoyltrimethyl-
• CAS No.: 120086-07-9
• Molecular Formula: C10H14OSn
• Molecular Weight: 268.931
• DSSTox Substance ID: DTXSID00452267
• Wikidata: Q82272779
• Mol file: 120086-07-9.mol

Synonyms:Stannane, benzoyltrimethyl-;120086-07-9;SCHEMBL3469174;DTXSID00452267

Chemical Property of Stannane, benzoyltrimethyl-

Chemical Property:

• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 2
• Exact Mass: 270.006668
• Heavy Atom Count: 12
• Complexity: 163

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C[Sn](C)(C)C(=O)C1=CC=CC=C1

Technology Process of Stannane, benzoyltrimethyl-

There total 4 articles about Stannane, benzoyltrimethyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

hexamethyldistannane (661-69-8) + benzoyl chloride (98-88-4) → phenyl(trimethylstannyl)methanone (120086-07-9)

Guidance literature:

trans benzyl(chloro)bis(triphenylphosphine)palladium(II); In tetrahydrofuran; byproducts: Me3SnCl; under Ar, 12 h reflux; removal of Me3SnCl in vac. or by addn. of saturated aq. KF soln. and filtration of Me3SnF, work-up of org. layer;

DOI:10.1016/0022-328X(92)80223-K

Reference yield:

iodobenzene (591-50-4) + carbon monoxide (201230-82-2) + hexamethyldistannane (661-69-8) → phenyl(trimethylstannyl)methanone (120086-07-9)

Guidance literature:

With tetrakis(triphenylphosphine) palladium⁽⁰⁾; In toluene; at 60 ℃; for 16h; under 7500.75 Torr; Sealed tube; Autoclave;

DOI:10.1016/j.jorganchem.2020.121351

Reference yield:

benzoyl fluoride (455-32-3) + hexamethyldistannane (661-69-8) → trimethyl(phenyl)stannane (934-56-5) + phenyl(trimethylstannyl)methanone (120086-07-9)

Guidance literature:

With 1,4-bis(dicyclohexylphosphino)butane; palladium dichloride; In o-xylene; at 110 ℃; for 10h; Inert atmosphere; Schlenk technique;

DOI:10.1002/adsc.201901223

upstream raw materials:

hexamethyldistannane

benzoyl chloride

benzoyl fluoride

iodobenzene

Downstream raw materials:

trimethyl(phenyl)stannane

C₆H₅COCCH₃CC₆H₅Sn(CH₃)3

(CH₃)3SnCCH₃CC₆H₅COC₆H₅

C₆H₅C(O)C(C₆H₅)C(C(O₂C₂H₅))Sn(CH₃)3