Stannane, trimethyl[(phenylmethoxy)methyl]-

Base Information

Chemical Name:Stannane, trimethyl[(phenylmethoxy)methyl]-
CAS No.:110615-32-2
Molecular Formula:C11H18OSn
Molecular Weight:284.973
Hs Code.:

Synonyms:

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Chemical Property of Stannane, trimethyl[(phenylmethoxy)methyl]-

Chemical Property:

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MSDS Files:: SDS file from LookChem

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Technology Process of Stannane, trimethyl[(phenylmethoxy)methyl]-

There total 1 articles about Stannane, trimethyl[(phenylmethoxy)methyl]- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

: 17946-71-3
(trimethylstannyl)lithium

: 17690-16-3
benzyl bromomethyl ether

: 110615-32-2
(benzyloxy)(trimethylstannyl)methane

Guidance literature:: In tetrahydrofuran; under argon; Me3SnLi in THF was cooled to 0 °C; bromo-compound was added over 1 min; warming to room temperature; stirring 1 h;; poured into NH4Cl-soln. and petroleum ether; organic layer was separated, washed (brine); dried (Na2SO4); filtered; concd.; chromatography (silica gel; ethyl acetate/petroleum ether 3:97); elem. anal.;;
DOI:10.1021/ja00211a024

Reference yield:

: 5707-04-0
Phenylselenyl chloride

: 110615-32-2
(benzyloxy)(trimethylstannyl)methane

: (1S,4S,7S)-3-[2-Benzyloxy-eth-(Z)-ylidene]-7-triethylsilanyloxy-7-vinyl-bicyclo[2.2.1]heptan-2-one

: (1S,3R,4R,7R)-3-(2-Benzyloxy-1-benzyloxymethyl-ethyl)-3-phenylselanyl-7-triethylsilanyloxy-7-vinyl-bicyclo[2.2.1]heptan-2-one

Guidance literature:: (benzyloxy)(trimethylstannyl)methane; (1S,4S,7S)-3-[2-Benzyloxy-eth-(Z)-ylidene]-7-triethylsilanyloxy-7-vinyl-bicyclo[2.2.1]heptan-2-one; With n-butyllithium; copper(I) bromide dimethylsulfide complex; boron trifluoride diethyl etherate; isopropylmagnesium bromide; In tetrahydrofuran; at -78 - -45 ℃; for 2.08333h;

Phenylselenyl chloride; In tetrahydrofuran; N,N,N,N,N,N-hexamethylphosphoric triamide; at 0 ℃; for 4h;
DOI:10.1016/S0040-4039(99)00743-1

Reference yield:

: 5707-04-0
Phenylselenyl chloride

: 110615-32-2
(benzyloxy)(trimethylstannyl)methane

: Methanesulfonic acid 2-benzyloxy-1-((1S,2S,4S,7S)-3-oxo-7-triethylsilanyloxy-7-vinyl-bicyclo[2.2.1]hept-2-yl)-ethyl ester

: (1S,3R,4R,7R)-3-(2-Benzyloxy-1-benzyloxymethyl-ethyl)-3-phenylselanyl-7-triethylsilanyloxy-7-vinyl-bicyclo[2.2.1]heptan-2-one

Guidance literature:: (benzyloxy)(trimethylstannyl)methane; Methanesulfonic acid 2-benzyloxy-1-((1S,2S,4S,7S)-3-oxo-7-triethylsilanyloxy-7-vinyl-bicyclo[2.2.1]hept-2-yl)-ethyl ester; With n-butyllithium; copper(I) bromide dimethylsulfide complex; boron trifluoride diethyl etherate; isopropylmagnesium bromide; In tetrahydrofuran; at -78 - -45 ℃; for 2.08333h;

Phenylselenyl chloride; In tetrahydrofuran; N,N,N,N,N,N-hexamethylphosphoric triamide; at 0 ℃; for 4h;
DOI:10.1016/S0040-4039(99)00743-1