N-Chlorobenzenemethanimine

Base Information

• Chemical Name: N-Chlorobenzenemethanimine
• CAS No.: 112129-04-1
• Molecular Formula: C7H6ClN
• Molecular Weight: 139.584
• DSSTox Substance ID: DTXSID90709313
• Nikkaji Number: J741.576A
• Mol file: 112129-04-1.mol

Synonyms:N-Chlorobenzenemethanimine;112129-04-1;N-Benzylidenehypochlorous amide;DTXSID90709313

Chemical Property of N-Chlorobenzenemethanimine

Chemical Property:

• XLogP3: 2.7
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 1
• Exact Mass: 139.0188769
• Heavy Atom Count: 9
• Complexity: 95.1

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C(C=C1)C=NCl

Technology Process of N-Chlorobenzenemethanimine

There total 8 articles about N-Chlorobenzenemethanimine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

hydrobenzamide (92-29-5) → benzaldehyde dimethyl acetal (1125-88-8) + N-chlorobenzenemethanimine (112129-04-1)

Guidance literature:

With methanol; tert-butylhypochlorite; at -65 - 20 ℃; for 0.166667h;

DOI:10.1021/jo960171f

Reference yield:

methanol (67-56-1) + hydrobenzamide (92-29-5) → benzaldehyde dimethyl acetal (1125-88-8) + N-chlorobenzenemethanimine (112129-04-1)

Guidance literature:

With tert-butylhypochlorite; at -65 - 20 ℃; for 0.166667h;

DOI:10.1021/jo960171f

Reference yield:

syn-benzaldehyde oxime (932-90-1,622-31-1,140461-24-1,140461-25-2,622-32-2) + diethyl ether (60-29-7,927820-24-4) + phosphorus trichloride (7719-12-2,52843-90-0) → N-chlorobenzenemethanimine (112129-04-1)

Guidance literature:

upstream raw materials:

(Z)-benzaldehyde oxime

benzaldehyde

methanol

hydrobenzamide

Downstream raw materials:

benzylideneamine*HCl

benzylamine

6-methoxy-3-phenyl-3a,4,6,6a-tetrahydro-furo<3,4-d>isoxazol-4-one

benzonitrile