Benzene, 1-(4,6-dimethyl-3-cyclohexen-1-yl)-4-methoxy-, trans-

Base Information

Chemical Name:Benzene, 1-(4,6-dimethyl-3-cyclohexen-1-yl)-4-methoxy-, trans-
CAS No.:112150-17-1
Molecular Formula:C15H20O
Molecular Weight:216.323
Hs Code.:

Synonyms:

Suppliers and Price of Benzene, 1-(4,6-dimethyl-3-cyclohexen-1-yl)-4-methoxy-, trans-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Total 1 raw suppliers

Chemical Property of Benzene, 1-(4,6-dimethyl-3-cyclohexen-1-yl)-4-methoxy-, trans-

Chemical Property:

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of Benzene, 1-(4,6-dimethyl-3-cyclohexen-1-yl)-4-methoxy-, trans-

There total 4 articles about Benzene, 1-(4,6-dimethyl-3-cyclohexen-1-yl)-4-methoxy-, trans- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

: 104-46-1,25086-72-0,63589-56-0
anethole

: 78-79-5,9003-31-0
isoprene

: 112150-17-1
(1SR,2SR)-4'-methoxy-2,4-dimethyl-1,2,3,6-tetrahydro-1,1'-biphenyl

Guidance literature:: With N,N’,N’’-tris(3,5-bis(trifluoromethyl)phenyl)thiophosphoramide; [Ru(4,4'-bis(trifluoromethyl)-2,2'-bipyridine)₃](3,5-bis(trifluoromethyl)benzenesulfonate)₂; In dichloromethane; at 20 ℃; for 0.333333h; Reagent/catalyst; Quantum yield; Inert atmosphere; Irradiation;
DOI:10.1021/jacs.9b01885

Reference yield: 98.0%

: 4180-23-8,25086-72-0,63589-56-0
E-1-(4'-methoxyphenyl)prop-1-ene

: 78-79-5,9003-31-0
isoprene

: 112150-17-1
(1SR,2SR)-4'-methoxy-2,4-dimethyl-1,2,3,6-tetrahydro-1,1'-biphenyl

Guidance literature:: With tris(2,2’--bipyrazyl)ruthenium(II) bis(tetrakis(3,5-bis(trifluoromethyl)phenyl)borate); In dichloromethane; at 20 ℃; for 1h; regioselective reaction; Irradiation;
DOI:10.15227/orgsyn.093.0178

Reference yield:

: 123-11-5
4-methoxy-benzaldehyde

: 112150-17-1
(1SR,2SR)-4'-methoxy-2,4-dimethyl-1,2,3,6-tetrahydro-1,1'-biphenyl

Guidance literature:: Multi-step reaction with 2 steps

1.1: potassium hexamethylsilazane; N,N,N,N,N,N-hexamethylphosphoric triamide / tetrahydrofuran / 0.17 h / 20 °C

1.2: 1 h / -78 - 20 °C

2.1: titanium(IV) oxide; lithium perchlorate / nitromethane / 2 h / 20 °C / UV-irradiation

With N,N,N,N,N,N-hexamethylphosphoric triamide; lithium perchlorate; potassium hexamethylsilazane; titanium(IV) oxide; In tetrahydrofuran; nitromethane; 2.1: |Diels-Alder Cycloaddition;
DOI:10.1021/acs.orglett.9b00526