Trimethyl{2-[(trimethylgermyl)methyl]phenyl}germane

Base Information

Chemical Name:Trimethyl{2-[(trimethylgermyl)methyl]phenyl}germane
CAS No.:113419-98-0
Molecular Formula:C13H24Ge2
Molecular Weight:325.514
Hs Code.:
DSSTox Substance ID:DTXSID80548132
Nikkaji Number:J1.729.302H
Wikidata:Q82426741
Mol file:113419-98-0.mol

Synonyms:113419-98-0;Trimethyl{2-[(trimethylgermyl)methyl]phenyl}germane;DTXSID80548132

Suppliers and Price of Trimethyl{2-[(trimethylgermyl)methyl]phenyl}germane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 1 raw suppliers

Chemical Property of Trimethyl{2-[(trimethylgermyl)methyl]phenyl}germane

Chemical Property:

Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:0
Rotatable Bond Count:3
Exact Mass:326.0310543
Heavy Atom Count:15
Complexity:198

Purity/Quality:: 99.90% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C[Ge](C)(C)CC1=CC=CC=C1[Ge](C)(C)C

Technology Process of Trimethyl{2-[(trimethylgermyl)methyl]phenyl}germane

There total 5 articles about Trimethyl{2-[(trimethylgermyl)methyl]phenyl}germane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

: 1529-47-1
chlorotrimethylgermane

: 105858-66-0
1,2-dihydro-1-magnesabenzocyclobutene

: 113419-98-0
1-trimethylgermyl-2-trimethylgermylmethylbenzene

Guidance literature:: In tetrahydrofuran; a suspn. of magnesacycle in THF was added at room temp. under nitrogen to a THF soln. of Me3GeCl, mixt. was stirred for 1 h; satd. aq. NH4Cl was added, aq. layer was extd. with Et2O, org. fractions were combined, dried, evapd., residue was purified by preparative GLC; elem. anal., high-resolution MS data;
DOI:10.1016/0022-328X(87)80301-7

Reference yield: 72.0%

: 54031-00-4
1-bromo-2-((trimethylstannyl)methyl)benzene

: 1529-47-1
chlorotrimethylgermane

: 1-(trimethylgermyl)-2-((tert-butyldimethylstannyl)methyl)benzene

: 113419-98-0
1-trimethylgermyl-2-trimethylgermylmethylbenzene

: 35569-11-0
di(t-butyl)dimethylstannane

: 3531-47-3
(t-butyl)trimethylstannane

: 35569-12-1
(tert-C₄H₉)3SnCH₃

Guidance literature:: With tert.-butyl lithium; In tetrahydrofuran; pentane; Ar atmosphere; cooling soln. of t-BuLi in pentane and THF (-80°C), addn. of Sn-compd., stirring (60 min, -80°C), quenching with Me3GeCl; hydrolysation (aq. NH4Cl), diln. (Et2O), sepn. of org. layer, washing (H2O), drying (MgSO4), evapn.;

Reference yield: 34.0%

: 54031-00-4
1-bromo-2-((trimethylstannyl)methyl)benzene

: 1529-47-1
chlorotrimethylgermane

: 113419-96-8
1-trimethylstannyl-2-((trimethylstannyl)methyl)benzene

: 114198-52-6
1-trimethylgermyl-2-((trimethylstannyl)methyl)benzene

: 113419-98-0
1-trimethylgermyl-2-trimethylgermylmethylbenzene

: 114198-53-7
1-(trimethylgermyl)methyl-2-(trimethylstannyl)benzene

Guidance literature:: With Mg; NH₄Cl; In tetrahydrofuran; using high-vac. techniques; mixt. of C6H4(Br)(CH2SnMe3), Mg in THF stirred at 60°C; after 24 h Me3GeCl added; Et2O and satd. NH4Cl added; org. fraction sepd.; aq. fraction extd. (Et2O); org. fractions combined; dried (MgSO4); filtered; evapd. to dryness;analyzed by NMR; isolated by chromy.;
DOI:10.1021/om011083a