1-trimethylgermyl-2-((trimethylstannyl)methyl)benzene

Base Information

Chemical Name:1-trimethylgermyl-2-((trimethylstannyl)methyl)benzene
CAS No.:114198-52-6
Molecular Formula:C₁₃H₂₄GeSn
Molecular Weight:371.634
Hs Code.:

Synonyms:1-trimethylgermyl-2-((trimethylstannyl)methyl)benzene

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Chemical Property of 1-trimethylgermyl-2-((trimethylstannyl)methyl)benzene

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Technology Process of 1-trimethylgermyl-2-((trimethylstannyl)methyl)benzene

There total 4 articles about 1-trimethylgermyl-2-((trimethylstannyl)methyl)benzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

: 54031-00-4
1-bromo-2-((trimethylstannyl)methyl)benzene

: 1529-47-1
chlorotrimethylgermane

: 114198-52-6
1-trimethylgermyl-2-((trimethylstannyl)methyl)benzene

Guidance literature:: With tert.-butyl lithium; In diethyl ether; pentane; Ar atmosphere; cooling soln. of t-BuLi in pentane and Et2O (-80°C), stirring (15 min), addn. of Sn-compd., stirring (1.5 h, -80°C), addn. of Me3GeCl, warming (room temp.); hydrolysation (aq. NH4Cl), diln. (Et2O), sepn. of org. layer, washing (H2O), drying (MgSO4), evapn.; elem. anal.;

Reference yield: 34.0%

: 54031-00-4
1-bromo-2-((trimethylstannyl)methyl)benzene

: 1529-47-1
chlorotrimethylgermane

: 113419-96-8
1-trimethylstannyl-2-((trimethylstannyl)methyl)benzene

: 114198-52-6
1-trimethylgermyl-2-((trimethylstannyl)methyl)benzene

: 113419-98-0
1-trimethylgermyl-2-trimethylgermylmethylbenzene

: 114198-53-7
1-(trimethylgermyl)methyl-2-(trimethylstannyl)benzene

Guidance literature:: With Mg; NH₄Cl; In tetrahydrofuran; using high-vac. techniques; mixt. of C6H4(Br)(CH2SnMe3), Mg in THF stirred at 60°C; after 24 h Me3GeCl added; Et2O and satd. NH4Cl added; org. fraction sepd.; aq. fraction extd. (Et2O); org. fractions combined; dried (MgSO4); filtered; evapd. to dryness;analyzed by NMR; isolated by chromy.;
DOI:10.1021/om011083a

Reference yield:

: 3433-80-5
1-Bromo-2-bromomethyl-benzene

: 114198-52-6
1-trimethylgermyl-2-((trimethylstannyl)methyl)benzene

Guidance literature:: Multi-step reaction with 2 steps

1: Mg; NH₄Cl / diethyl ether; pentane

2: tert-butyllithium; NH₄Cl / diethyl ether; pentane

With Mg; NH₄Cl; tert-butyllithium; In diethyl ether; pentane;
DOI:10.1021/om011083a