Dicyclohexyl(phenyl)methanol

Base Information

• Chemical Name: Dicyclohexyl(phenyl)methanol
• CAS No.: 87839-87-0
• Molecular Formula: C19H28 O
• Molecular Weight: 272.431
• European Community (EC) Number: 684-930-8
• NSC Number: 121815
• DSSTox Substance ID: DTXSID90298232
• Wikidata: Q82039910
• Mol file: 87839-87-0.mol

Synonyms:87839-87-0;dicyclohexyl(phenyl)methanol;NSC121815;DTXSID90298232;DICYCLOHEXYL-PHENYL-METHANOL;AKOS024322777;NSC-121815

Chemical Property of Dicyclohexyl(phenyl)methanol

Chemical Property:

• Vapor Pressure: 2.45E-07mmHg at 25°C
• Boiling Point: 406.5°C at 760 mmHg
• Flash Point: 152.4°C
• Density: 1.039g/cm³
• XLogP3: 5.6
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 3
• Exact Mass: 272.214015512
• Heavy Atom Count: 20
• Complexity: 262

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1CCC(CC1)C(C2CCCCC2)(C3=CC=CC=C3)O

Technology Process of Dicyclohexyl(phenyl)methanol

There total 14 articles about Dicyclohexyl(phenyl)methanol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

benzoic acid ethyl ester (93-89-0,99341-95-4) + cyclohexylmagnesium bromide (931-50-0) → α,α-Dicyclohexylbenzolmethanol (87839-87-0)

Guidance literature:

In diethyl ether; for 16h; Heating;

Reference yield: 74.0%

B-methoxydicyclohexylborane (32705-46-7) + (α,α-dichlorobenzyl)lithium (3141-47-7) → α,α-Dicyclohexylbenzolmethanol (87839-87-0)

Guidance literature:

With sodium hydroxide; dihydrogen peroxide; In tetrahydrofuran; -100°C, after 15 min warming to room temp. with stirring, keeping overnight, treating with H2O2-NaOH at 0°C, stirring for 1 h at room temp. and for 15 min at 50°C; Aq. phase is satd. with K2CO3, extd. with diethyl ether, combined phases are dried (K2CO3), concd., chromd. (silicagel, ethyl acetate-petroleum ether);

DOI:10.1016/0022-328X(89)87060-3

Reference yield:

chloro-dicyclohexyl-phenyl-methane (51046-32-3) → α,α-Dicyclohexylbenzolmethanol (87839-87-0)

Guidance literature:

With acetone; silver(l) oxide;

upstream raw materials:

diethyl ether

Cyclohexyl phenyl ketone

cyclohexylmagnesiumchloride

dicyclohexyl ketone

Downstream raw materials:

(Bromdicyclohexylmethyl)benzol

9-Phenylfluorene

dicyclohexyl-phenyl-methane

cyclohexyl-cyclohexylidene-phenyl-methane