32705-46-7Relevant articles and documents
Boron complexes of S-trityl-L-cysteine and S-tritylglutathione
Díaz, Sandra,González, Asensio,González De Riancho, Sandra,Rodríguez, Ana
, p. 25 - 30 (2000)
S-Trityl-L-cysteine and S-tritylglutathione have been converted to 1,3,2-oxazaborolidine-5-ones by reaction with B-methoxydi-alkylborane derivatives. The synthesis of dicyclohexyl[S-trityl-(R)-cysteinato-O,N]boron (2), diisopinocampheyl[S-trityl-(R)-cysteinato-O,N]boron (3) and 9-borabicyclo[3.3.1]non-9-yl[S-tritylglutathionato-O,N]boron (5), dicyclohexyl[S-tritylglutathionato-O,N]boron (6) and diisopinocampheyl[S-tritylglutathionato-O,N]boron (7) from S-trityl-L-cysteine and S-tritylglutathione, respectively, with potential application in boron neutron capture therapy is reported. The structure of 9-borabicyclo[3.3.1]non-9-yl[S-trityl-(R)-cysteinato-O,N]boron 1 has been determined by X-ray diffraction.
Method for Preparing Methoxyboranes and for Producing Methanol
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Paragraph 0183; 0184; 0187; 0188, (2018/12/04)
The present disclosure relates to a method for preparing methoxyboranes by dismutation of formic acid or at least one of the derivatives thereof or a mixture of formic acid and at least one of the derivatives thereof, in the presence of an organoborane, and optionally an organic or inorganic base.
Poly(propylene sulfide)-borane: Convenient and versatile reagent for organic synthesis
Smith, Keith,Balakit, Asim A.,El-Hiti, Gamal A.
, p. 7834 - 7839 (2012/09/22)
Poly(trimethylene sulfide)-borane adduct has been used as an efficient borane reagent in hydroboration reactions to produce various organoboranes, which have then been used without isolation in further reactions that involve single, double and triple migrations of alkyl groups. The presence of the polymer causes no problems, but there are practical advantages associated with its use, including lack of odour and easy recoverability.
