Chloro[tris(pentafluorophenyl)]germane

Base Information

• Chemical Name: Chloro[tris(pentafluorophenyl)]germane
• CAS No.: 1259-89-8
• Molecular Formula: C18ClF15Ge
• Molecular Weight: 609.217
• DSSTox Substance ID: DTXSID90507018
• Nikkaji Number: J3.293.282G
• Wikidata: Q82363025
• Mol file: 1259-89-8.mol

Synonyms:Chloro[tris(pentafluorophenyl)]germane;1259-89-8;DTXSID90507018;tris(pentafluorophenyl)chlorogermane;Tris(pentafluorophenyl)germanium chloride

Chemical Property of Chloro[tris(pentafluorophenyl)]germane

Chemical Property:

• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 15
• Rotatable Bond Count: 3
• Exact Mass: 609.8660779
• Heavy Atom Count: 35
• Complexity: 612

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1(=C(C(=C(C(=C1F)F)[Ge](C2=C(C(=C(C(=C2F)F)F)F)F)(C3=C(C(=C(C(=C3F)F)F)F)F)Cl)F)F)F

Technology Process of Chloro[tris(pentafluorophenyl)]germane

There total 26 articles about Chloro[tris(pentafluorophenyl)]germane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

hexakis(pentafluorophenyl)digermane (42437-33-2) + mercury dichloride → Chloro[tris(perfluorophenyl)]-germane (1259-89-8)

Guidance literature:

In tetrahydrofuran; 70°C, 1 h;

DOI:10.1016/S0022-328X(00)83773-0

Reference yield: 97.0%

hexakis(pentafluorophenyl)digermane (42437-33-2) → Chloro[tris(perfluorophenyl)]-germane (1259-89-8)

Guidance literature:

With copper dichloride; 100°C, 0.75 h;

Reference yield: 95.8%

tris{tris(pentafluorophenyl)germyl}praseodymium-bis{tris(pentafluorophenyl)germyl}mercury → Chloro[tris(perfluorophenyl)]-germane (1259-89-8)

Guidance literature:

With hydrogenchloride; In tetrahydrofuran; reaction with HCl at 20°C for 12 h, subsequent heating at 70°C for 2 h;

DOI:10.1016/S0020-1693(00)93820-9

upstream raw materials:

bismuth(III) chloride

1,1,1-Triethyl-2,2,2-tris-pentafluorophenyl-digermane

hexakis(pentafluorophenyl)digermane

ethylmercury(II) chloride

Downstream raw materials:

hexaphenylditin

butyl tris-(pentafluoro phenyl) germane

tris(pentafuorophenyl)germane

(C₆F₅)3GeP(C₆H₅)Ge(C₆F₅)3