Stannane, tricyclohexyl-2-propenyl-

Base Information

• Chemical Name: Stannane, tricyclohexyl-2-propenyl-
• CAS No.: 13121-83-0
• Molecular Formula: C21H38Sn
• Molecular Weight: 409.243
• Mol file: 13121-83-0.mol

Synonyms:

Chemical Property of Stannane, tricyclohexyl-2-propenyl-

Chemical Property:

Purity/Quality:

99.90% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Stannane, tricyclohexyl-2-propenyl-

There total 1 articles about Stannane, tricyclohexyl-2-propenyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

tricyclohexyltin(IV) chloride (3091-32-5) + allyl bromide (106-95-6) → Cy3SnCH2CHCH2 (13121-83-0)

Guidance literature:

With magnesium; In tetrahydrofuran; soln. of trialkyltin chloride and 5-fold excess of allyl bromide in THF was added (at a rate to maintain a gentle reflux) to 5-fold excess of Mg with vigorous stirring under Ar; chromy. (silica gel, pentane), elem. anal.;

DOI:10.1016/0022-328X(92)83265-J

Reference yield:

Cy3SnCH2CHCH2 (13121-83-0) + titanium tetrachloride (7550-45-0) → allyl titanium trichloride + tricyclohexyltin(IV) chloride (3091-32-5)

Guidance literature:

In chloroform-d1; react. with TiCl4 (1 equiv) at 30°C under complete and rapid formation of Cy3SnCl and a brown ppt. of allyl titanium trichloride;

DOI:10.1016/S0020-1693(00)83155-2

Reference yield:

Cy3SnCH2CHCH2 (13121-83-0) + oxygen (80937-33-3) → allylperoxytricyclohexyltin (144026-92-6) + 3-(tricyclohexylstannyl)allyl hydroperoxide (144026-93-7)

Guidance literature:

With tetraphenylporphirin; lithium perchlorate; In diethyl ether; Irradiation (UV/VIS); vigorously stirring of soln. of tricyclohexyl (prop-2-enyl)tin and tetraphenylporphirin in Et2O and 4 mol/dm**-3 soln. of LiClO4 in Et2O under oxygen; irradn. with light from 400 W sodium lamp for 3 h at room temp.; removal of solvent; identification by NMR; Kinetics;

DOI:10.1016/S0022-328X(00)00362-4

upstream raw materials:

tricyclohexyltin(IV) chloride

allyl bromide

Downstream raw materials:

tris(cyclohexyl)tin bromide

tricyclohexyltin(IV) chloride

N-allyl-N'-tricyclohexylstannylhydrazodicarboxylate

(CH₂CHCH₂)(C₆H₅C₂N₃O₂)Sn(C₆H₁₁)3