1,4-Benzenediamine, N,N-dimethyl-N'-(4-methylphenyl)-

Base Information

Chemical Name:1,4-Benzenediamine, N,N-dimethyl-N'-(4-methylphenyl)-
CAS No.:132540-71-7
Molecular Formula:C15H18N2
Molecular Weight:226.321
Hs Code.:
DSSTox Substance ID:DTXSID00567547
Nikkaji Number:J1.945.232H
Wikidata:Q82453457

Synonyms:132540-71-7;SCHEMBL11723882;DTXSID00567547;N~1~,N~1~-Dimethyl-N~4~-(4-methylphenyl)benzene-1,4-diamine

Suppliers and Price of 1,4-Benzenediamine, N,N-dimethyl-N'-(4-methylphenyl)-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 4 raw suppliers

Chemical Property of 1,4-Benzenediamine, N,N-dimethyl-N'-(4-methylphenyl)-

Chemical Property:

XLogP3:4.4
Hydrogen Bond Donor Count:1
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:3
Exact Mass:226.146998583
Heavy Atom Count:17
Complexity:211

Purity/Quality:: 98%min ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC1=CC=C(C=C1)NC2=CC=C(C=C2)N(C)C

Technology Process of 1,4-Benzenediamine, N,N-dimethyl-N'-(4-methylphenyl)-

There total 5 articles about 1,4-Benzenediamine, N,N-dimethyl-N'-(4-methylphenyl)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

: 106-49-0,12221-03-3
p-toluidine

: 7353-91-5
4-dimethylaminophenylmagnesium bromide

: 366-29-0
N,N,N',N'-tetramethylbenzidine

: 132540-71-7
4-methyl-4'-(N,N-dimethylamino)diphenylamine

Guidance literature:: p-toluidine; With n-butyllithium; dichloro(N,N,N’,N‘-tetramethylethylenediamine)zinc; In tetrahydrofuran; hexane; at 0 - 20 ℃; for 0.5h; Inert atmosphere; Schlenk technique;

4-dimethylaminophenylmagnesium bromide; With 1,3-dimethyl-3,4,5,6-tetrahydro-2(1H)-pyrimidinone; bis(acetylacetonate)nickel(II); 1,2-dichloro-2-methylpropane; In tetrahydrofuran; hexane; at 0 - 20 ℃; for 3h; Inert atmosphere; Schlenk technique;
DOI:10.1021/ol302688u

Reference yield: 92.0%

: 586-77-6
4-bromo-N,N-dimethylaniline

: 106-49-0,12221-03-3
p-toluidine

: 132540-71-7
4-methyl-4'-(N,N-dimethylamino)diphenylamine

Guidance literature:: With [1,3-bis[2,6-bis[3-methyl-1-(2-methylpropyl)butyl]phenyl]-4,5-dichloro-1,3-dihydro-2H-imidazol-2-ylidene]chloro[(1,2,3-η)-1-phenyl-2-propen-1-yl]palladium; potassium tert-butylate; at 50 ℃; for 0.25h; Sealed tube;
DOI:10.1021/acs.joc.1c01057

Reference yield: 43.0%

: 109-72-8,29786-93-4
n-butyllithium

: 99-99-0
1-methyl-4-nitrobenzene

: 586-77-6
4-bromo-N,N-dimethylaniline

: 132540-71-7
4-methyl-4'-(N,N-dimethylamino)diphenylamine

Guidance literature:: n-butyllithium; 4-bromo-N,N-dimethylaniline; In tetrahydrofuran; hexane; at -78 ℃; for 2h;

1-methyl-4-nitrobenzene; In tetrahydrofuran; hexane; at -78 - 20 ℃;
DOI:10.1016/j.tetlet.2003.07.002